{"id":"W2067904223","doi":"10.1021/om070238x","title":"Rhodium Silyl Hydrides in Oxidation State +5:  Classical or Nonclassical?","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Chemistry; Steric effects; Rhodium; Hydride; Silylation; Conformational isomerism; Crystallography; Potential energy surface; Stereochemistry; Oxidation state; Bond length; Computational chemistry; Medicinal chemistry; Molecule; Crystal structure; Catalysis; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001382931,0.0001788237,0.0001902052,0.0001042187,0.0001301304,0.0003607725,0.0004888197,0.0002830329,0.001948163],"category_scores_gemma":[0.0002002992,0.0001028638,0.0001744736,0.0000723081,0.0003510247,0.000301929,0.0003599891,0.0002219914,0.0001955428],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002663412,"about_ca_system_score_gemma":0.0001312983,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006243471,"about_ca_topic_score_gemma":0.001182373,"domain_scores_codex":[0.9999332,0.000007435439,0.000002256573,0.00001040986,0.00002233511,0.0000243505],"domain_scores_gemma":[0.9999599,0.000007990806,0.000008596953,0.00001130139,0.000005112769,0.000007091733],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00192335,0.000296716,0.01164775,0.001934097,0.0001655455,0.001591056,0.0005486054,0.03512045,0.7465343,0.1382995,0.002704978,0.05923368],"study_design_scores_gemma":[0.000443247,0.004801747,0.02672852,0.0001638038,0.0002526873,0.001761648,0.001253154,0.2185824,0.6980085,0.02431089,0.02354513,0.0001481174],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9915174,0.0003902917,0.001528309,0.0000911834,0.00001197917,0.00001209258,0.00003945405,0.00004936947,0.006359948],"genre_scores_gemma":[0.9986449,0.0001353046,0.0006225669,0.00001715151,0.000001995354,0.000005388926,0.00004788599,0.000004831164,0.0005199588],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001948163,"threshold_uncertainty_score":0.006517291,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01919768308569367,"score_gpt":0.2545122035630852,"score_spread":0.2353145204773916,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}