{"id":"W2067904223","doi":"10.1021/om070238x","title":"Rhodium Silyl Hydrides in Oxidation State +5:  Classical or Nonclassical?","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"Brock University","funders":"","keywords":"Chemistry; Steric effects; Rhodium; Hydride; Silylation; Conformational isomerism; Crystallography; Potential energy surface; Stereochemistry; Oxidation state; Bond length; Computational chemistry; Medicinal chemistry; Molecule; Crystal structure; Catalysis; Metal; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0006772703,0.0003862154,0.0005893396,0.0003317067,0.0001151751,0.0001228619,0.0005207045,0.0002038312,0.03795397],"category_scores_gemma":[0.0003802538,0.0003260681,0.0002070929,0.001214287,0.0001723522,0.0002739246,0.0001955032,0.0003795178,0.0004665915],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003115639,"about_ca_system_score_gemma":0.0001224082,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003611113,"about_ca_topic_score_gemma":0.0007675844,"domain_scores_codex":[0.9971483,0.00003107178,0.0008575772,0.0006660981,0.0005411759,0.000755831],"domain_scores_gemma":[0.9982355,0.0004643168,0.0002236506,0.0007176418,0.000071845,0.0002870471],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002503798,0.0009068761,0.005006561,0.0001304272,0.0001692089,0.0001649744,0.0004625155,0.0000166423,0.7389076,0.001161595,0.0001918059,0.2526314],"study_design_scores_gemma":[0.001441236,0.00007765499,0.02687902,0.00006696552,0.0001589655,0.00004314737,0.0006353584,0.000612659,0.6122639,0.001038474,0.3556168,0.001165867],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9682353,0.0001388704,0.002012413,0.0005588298,0.0001045967,0.0001018775,0.00002385744,0.0001714826,0.02865277],"genre_scores_gemma":[0.9679129,0.0001328413,0.001112813,0.000129896,0.000250844,0.00001557516,0.00009284748,0.00008477475,0.03026756],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.355425,"threshold_uncertainty_score":0.9999191,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01919768308569367,"score_gpt":0.2545122035630852,"score_spread":0.2353145204773916,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}