{"id":"W2068052889","doi":"10.1021/ja105075h","title":"Dihydrogen Activation by Antiaromatic Pentaarylboroles","year":2010,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":190,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; Alberta Innovates; Jyväskylän Yliopisto","keywords":"Antiaromaticity; Chemistry; Lewis acids and bases; Frustrated Lewis pair; Boron; Hydrogen; Hydrogen bond; Catalysis; Yield (engineering); Metal; Photochemistry; Inorganic chemistry; Medicinal chemistry; Computational chemistry; Molecule; Organic chemistry; Aromaticity","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006514628,0.0001513695,0.0000971543,0.0001003398,0.00009597163,0.0001955145,0.0001413735,0.0001792593,0.001345546],"category_scores_gemma":[0.00008847031,0.00008970858,0.00008723124,0.00006378223,0.000116303,0.0003076345,0.0002087501,0.0002207396,0.0004063286],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001413414,"about_ca_system_score_gemma":0.0001055362,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001632491,"about_ca_topic_score_gemma":0.0003764272,"domain_scores_codex":[0.9999406,0.000009525656,0.000003288558,0.00001201494,0.00001136136,0.0000231466],"domain_scores_gemma":[0.9999704,0.00000587422,0.000008660802,0.000004046852,0.000003572629,0.000007400859],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009707949,0.00002242737,0.0002414545,0.00004778823,0.000004157962,0.00007218237,0.00004608025,0.0001904193,0.9924284,0.001969245,0.0001554504,0.00472534],"study_design_scores_gemma":[0.00000947529,0.0001583406,0.0003492399,0.000002183667,0.000003043964,0.0001214201,0.00001826551,0.0006834685,0.9946175,0.0001921293,0.003840227,0.000004689633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9880585,0.000741142,0.003035939,0.00007597209,0.00002815681,0.00001108224,0.00009588114,0.00008514005,0.007868166],"genre_scores_gemma":[0.9964773,0.0003099898,0.001164609,0.00003079814,0.000005954672,0.000006414365,0.00007345375,0.00001741524,0.001914123],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001345546,"threshold_uncertainty_score":0.004501283,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004126432017510235,"score_gpt":0.2250090365386699,"score_spread":0.2208826045211597,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}