{"id":"W2068131851","doi":"10.1002/1521-3900(200010)161:1<141::aid-masy141>3.0.co;2-k","title":"New epoxide initiators for the controlled synthesis of functionalized polyisobutylenes","year":2000,"lang":"en","type":"article","venue":"Macromolecular Symposia","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"","keywords":"Epoxide; SN2 reaction; Carbocation; Isobutylene; Isomerization; Polymer chemistry; Polymerization; Chemistry; Materials science; Photochemistry; Copolymer; Polymer; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004087372,0.0002930987,0.0005729974,0.00002976063,0.0001402794,0.0000414635,0.0005009393,0.0001816517,0.02511944],"category_scores_gemma":[0.0007129297,0.0002253511,0.0005201746,0.0001524989,0.0001071552,0.00003563476,0.00004254418,0.0001243462,0.00002854167],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005363815,"about_ca_system_score_gemma":0.000180638,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006989323,"about_ca_topic_score_gemma":0.000001818034,"domain_scores_codex":[0.9982651,0.00007412751,0.0005693316,0.0003823253,0.000363179,0.0003459442],"domain_scores_gemma":[0.9970853,0.001738647,0.0001998405,0.0007664706,0.00007709407,0.0001326071],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0009459716,0.00006838125,0.00006363205,0.00009555501,0.0005638645,0.000009411036,0.00006792821,0.00001993049,0.9517202,0.000620064,0.0006190788,0.04520592],"study_design_scores_gemma":[0.003347754,0.00001454812,0.00003074339,0.00006920891,0.0005013464,0.00007475141,0.0000651493,0.0002664958,0.9489884,0.000375293,0.04603089,0.0002354088],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.705364,0.01666883,0.07786974,0.006137228,0.001018562,0.00228737,0.0005037783,0.0007405563,0.1894099],"genre_scores_gemma":[0.9727035,0.0001759241,0.01117969,0.0002126208,0.0004088935,0.0003724359,0.00001925419,0.0001277568,0.0147999],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2673395,"threshold_uncertainty_score":0.9757717,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009263522414127541,"score_gpt":0.2499303126721173,"score_spread":0.2406667902579898,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}