{"id":"W2068192381","doi":"10.1021/om700811e","title":"Catalytic Alkyne Hydrothiolation with Alkanethiols using Wilkinson's Catalyst","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":112,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Alkyne; Chemistry; Catalysis; Reductive elimination; Migratory insertion; Alkyl; Oxidative addition; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000611325,0.000364849,0.0003806076,0.0002377974,0.0001709381,0.00007712204,0.0003956201,0.0002897281,0.0005889718],"category_scores_gemma":[0.0001793537,0.0003344976,0.00009964026,0.0006295131,0.0001505253,0.0003008402,0.00007761438,0.0003453244,0.00006657084],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003671418,"about_ca_system_score_gemma":0.0001343579,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001888745,"about_ca_topic_score_gemma":0.0001247177,"domain_scores_codex":[0.9979352,0.00001832316,0.0004519268,0.0005331648,0.0004983431,0.0005630096],"domain_scores_gemma":[0.9982769,0.0002548379,0.0002834813,0.0008662901,0.0001242526,0.0001942487],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006403262,0.000129808,0.006071629,0.0001026919,0.0001184374,0.00007523566,0.0002237913,0.00003884931,0.9861226,0.0002691633,0.0000392539,0.006744522],"study_design_scores_gemma":[0.0003442278,0.00003092218,0.0006321666,0.00009616467,0.0001513766,0.0001057297,0.0001388996,0.0003767896,0.989697,0.0001658054,0.007754643,0.0005063163],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9656895,0.0001499367,0.01457122,0.00006111443,0.00003856407,0.0001665913,0.00001840131,0.0005339673,0.01877066],"genre_scores_gemma":[0.9854311,0.00001603988,0.01336884,0.0001113012,0.0002039352,0.0000108516,0.0001367562,0.0001275092,0.0005936759],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01974154,"threshold_uncertainty_score":0.9999107,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01834845217474343,"score_gpt":0.2517797740614237,"score_spread":0.2334313218866802,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}