{"id":"W2068192381","doi":"10.1021/om700811e","title":"Catalytic Alkyne Hydrothiolation with Alkanethiols using Wilkinson's Catalyst","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Sulfur-Based Synthesis Techniques","field":"Chemistry","cited_by":112,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Alkyne; Chemistry; Catalysis; Reductive elimination; Migratory insertion; Alkyl; Oxidative addition; Combinatorial chemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001560378,0.000327763,0.0001456834,0.0002009747,0.0001234387,0.0002166698,0.0002154334,0.0001803274,0.0006115495],"category_scores_gemma":[0.0001461272,0.0001280662,0.0001657206,0.000140493,0.0002876741,0.000264994,0.0002392661,0.0002593239,0.0002609683],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001775912,"about_ca_system_score_gemma":0.0001534165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003873223,"about_ca_topic_score_gemma":0.0007279755,"domain_scores_codex":[0.9999124,0.00001423662,0.000007919039,0.00001929988,0.00002374635,0.00002253664],"domain_scores_gemma":[0.9999558,0.00001134133,0.00001197997,0.000005704336,0.000005757536,0.000009489007],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006864679,0.00001462011,0.0001301756,0.00008674905,0.00001311246,0.0001854933,0.00004189185,0.0001949437,0.9901189,0.00120063,0.0001057286,0.007839078],"study_design_scores_gemma":[0.000005045026,0.00003257319,0.0001010015,0.000001302041,0.000004930368,0.00005935354,0.000003573859,0.000339529,0.9978372,0.0000516523,0.001560677,0.000003287398],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9691185,0.004137439,0.01923189,0.0002243744,0.0001212703,0.00006897264,0.00008602928,0.0002346583,0.006776818],"genre_scores_gemma":[0.9891333,0.001422961,0.006181929,0.00004010387,0.0000195692,0.00001264372,0.00004825916,0.00002492463,0.003116261],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006115495,"threshold_uncertainty_score":0.00204581,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01834845217474343,"score_gpt":0.2517797740614237,"score_spread":0.2334313218866802,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}