{"id":"W2068225337","doi":"10.1021/ie800887v","title":"Kinetics and Modeling of Free-Radical Batch Polymerization of Nonionized Methacrylic Acid in Aqueous Solution","year":2008,"lang":"en","type":"article","venue":"Industrial & Engineering Chemistry Research","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Monomer; Methacrylic acid; Polymerization; Aqueous solution; Radical polymerization; Polymer chemistry; Chemistry; Diffusion; Kinetics; Bulk polymerization; Polymer; Kinetic chain length; Molar mass distribution; Chain transfer; Thermodynamics; Physical chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004156608,0.0006705694,0.0007072334,0.0003132113,0.0002474602,0.000526392,0.001027087,0.0009224855,0.001105058],"category_scores_gemma":[0.0005562336,0.0004292058,0.0008484728,0.0002289693,0.0002813798,0.0006472218,0.0001340185,0.0006945106,0.0006276808],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001029947,"about_ca_system_score_gemma":0.0006949463,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.006295928,"about_ca_topic_score_gemma":0.002096589,"domain_scores_codex":[0.9998646,0.00001097683,0.000008012876,0.000035059,0.00005805803,0.00002331663],"domain_scores_gemma":[0.9997846,0.00009889096,0.00003583643,0.00001252897,0.00005384182,0.0000142435],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002511278,0.000157351,0.001112533,0.0003228034,0.0000415414,0.0002920263,0.0001139066,0.534175,0.4551569,0.00212068,0.0001853059,0.006070818],"study_design_scores_gemma":[0.000009761497,0.00008103576,0.0003961476,0.000004555126,0.000009425037,0.0000278383,0.000006819155,0.9377544,0.06118597,0.0001688722,0.0003439903,0.00001113408],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8372936,0.001890957,0.1541414,0.0002261615,0.0001238649,0.0002220966,0.0006225299,0.0006714436,0.004807787],"genre_scores_gemma":[0.9681836,0.001435146,0.02273376,0.00002744924,0.00001463021,0.0002340906,0.0003774121,0.00005947452,0.006934356],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006295928,"threshold_uncertainty_score":0.01251853,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08494180170020696,"score_gpt":0.3013936422962816,"score_spread":0.2164518405960747,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}