{"id":"W2068282272","doi":"10.1002/chem.200601878","title":"A Bioorganometallic Approach for the Electrochemical Detection of Proteins: A Study on the Interaction of Ferrocene–Peptide Conjugates with Papain in Solution and on Au Surfaces","year":2007,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Ferrocene Chemistry and Applications","field":"Chemistry","cited_by":83,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Peptide; Chemistry; Papain; Amino acid; Stereochemistry; Trifluoroacetic acid; Conjugate; Ferrocene; Cyclic voltammetry; Enzyme; Biochemistry; Organic chemistry; Electrochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002293945,0.0003815699,0.0003652551,0.0001710449,0.0002015938,0.0003240553,0.0005303796,0.0008150894,0.0006359687],"category_scores_gemma":[0.0002224104,0.0001981988,0.0002321902,0.0001072872,0.0002737274,0.0002846913,0.0001728767,0.0007162754,0.0002779978],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003793242,"about_ca_system_score_gemma":0.0001598371,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005184381,"about_ca_topic_score_gemma":0.0006915264,"domain_scores_codex":[0.9997535,0.00003665834,0.000009487729,0.00006927189,0.00009213568,0.00003886053],"domain_scores_gemma":[0.9999099,0.00002969699,0.00001583352,0.000007942482,0.00002217181,0.00001440968],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001735057,0.00001097373,0.00002352972,0.00004368382,0.000003859386,0.00004229571,0.00001400107,0.00002679895,0.9989225,0.00005638897,0.000007185823,0.0008312886],"study_design_scores_gemma":[0.000003634539,0.0001330506,0.0002582333,0.000002666269,0.000005954334,0.0002627397,0.000009621817,0.0003962153,0.9980527,0.00001944608,0.0008520386,0.00000357713],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.941025,0.01132667,0.04378242,0.0003575326,0.0001033971,0.00009727441,0.00007874984,0.0001569548,0.003072025],"genre_scores_gemma":[0.9700537,0.003300048,0.02265673,0.0001425107,0.00003708337,0.0000473286,0.0000892863,0.00002137915,0.003651937],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008150894,"threshold_uncertainty_score":0.002752185,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02538144790680621,"score_gpt":0.2401026564433812,"score_spread":0.214721208536575,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}