{"id":"W2068326631","doi":"10.1039/c002503h","title":"Experimental and theoretical study on activation of the C–H bond in pyridine by [Mm]− (M = Cu, Ag, Au, m = 1–3)","year":2010,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Advanced Chemical Physics Studies","field":"Physics and Astronomy","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"Dalian Institute of Chemical Physics; Natural Sciences and Engineering Research Council of Canada; National Natural Science Foundation of China; Wilfrid Laurier University","keywords":"Chemistry; Metal; Pyridine; Yield (engineering); Crystallography; Atom (system on chip); Molecule; Materials science; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003548634,0.0003666173,0.0003131704,0.0002191729,0.0005435767,0.000251969,0.001327573,0.0005413755,0.003060744],"category_scores_gemma":[0.0007632388,0.0002029357,0.0002060571,0.000332898,0.0008032753,0.0005384635,0.0003133878,0.0005495216,0.0001695687],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006724538,"about_ca_system_score_gemma":0.0002051144,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001150031,"about_ca_topic_score_gemma":0.0007541497,"domain_scores_codex":[0.9997478,0.00004326561,0.000005476271,0.00004650668,0.0001169501,0.00003997936],"domain_scores_gemma":[0.9996269,0.0002396718,0.00004713417,0.00004322561,0.0000310212,0.00001208998],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001010142,0.0003767179,0.005873822,0.001762289,0.00009376632,0.001170708,0.0005170585,0.03559724,0.9024131,0.03638756,0.0006598912,0.01413768],"study_design_scores_gemma":[0.0000731446,0.0005469306,0.00511751,0.00001595846,0.0000300712,0.0003205493,0.0001819246,0.1021422,0.8856105,0.003832183,0.002093413,0.0000356713],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9860984,0.001040371,0.005446468,0.00009901691,0.00001447182,0.00002611869,0.0001391703,0.00005416705,0.007081811],"genre_scores_gemma":[0.9975655,0.0003169252,0.001681602,0.00001107738,0.000005320812,0.00001537635,0.00007317,0.000005195346,0.0003258512],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003060744,"threshold_uncertainty_score":0.01023924,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006372581541936176,"score_gpt":0.260309734235566,"score_spread":0.2539371526936299,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}