{"id":"W2068803426","doi":"10.1039/b500993f","title":"Hexafluoroantimony(v) salts of the cationic Ti(iv) fluoride non metallocene complexes [TiF3(MeCN)3]+ and [TiF2L]2+ (L = 15-Crown-5 and 18-Crown-6). Preparation, characterization and thermodynamic stability","year":2005,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":27,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Cationic polymerization; Chemistry; Ligand (biochemistry); Fluoride; Metallocene; Titanium; Inorganic chemistry; Lewis acids and bases; Medicinal chemistry; Crystallography; Polymer chemistry; Organic chemistry; Polymerization; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001878952,0.00026364,0.0003118961,0.00006298696,0.0005360855,0.00008515467,0.0001530494,0.0001984755,0.0005525606],"category_scores_gemma":[0.00001422167,0.0002140968,0.00008199894,0.0002158804,0.0003157711,0.0003662189,0.00002639371,0.0003071575,0.000003385107],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008593213,"about_ca_system_score_gemma":0.0001002736,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000206603,"about_ca_topic_score_gemma":0.0002725488,"domain_scores_codex":[0.9985,0.00005465448,0.0005225752,0.0004461925,0.000221734,0.0002547811],"domain_scores_gemma":[0.9989891,0.00008791039,0.0002204368,0.0004685493,0.0001307755,0.0001032304],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008460465,0.0001510166,0.001352352,0.0002008388,0.0001350615,3.395623e-7,0.001807492,0.0001047594,0.9897165,0.0001772648,0.00001346047,0.006256338],"study_design_scores_gemma":[0.002377036,0.0001136468,0.108123,0.0001979911,0.0007162379,0.0001728466,0.0004328069,0.08080918,0.7994605,0.0003256313,0.006483223,0.0007878706],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9926287,0.0004444603,0.005055095,0.0006320011,0.0001296233,0.0002892031,0.0001892005,0.00007150511,0.0005602362],"genre_scores_gemma":[0.997936,0.0007269235,0.000241235,0.00004594076,0.00006450865,0.00002787701,0.000128617,0.00003368298,0.0007952816],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.190256,"threshold_uncertainty_score":0.8730616,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008813592324841574,"score_gpt":0.2187002637147352,"score_spread":0.2098866713898936,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}