{"id":"W2068807017","doi":"10.1021/ol061772o","title":"[1,2]- or [2,3]-Rearrangement of Onium Ylides of Allyl and Benzyl Ethers and Sulfides via in Situ-Generated Iodonium Ylides","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Oxonium ion; Sulfonium; Chemistry; Ylide; Carbene; Carbenoid; Onium; Medicinal chemistry; Rhodium; Catalysis; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001512381,0.0002137235,0.0003427233,0.0001218438,0.00003792418,0.00002232533,0.0001145468,0.0001191351,0.0003256742],"category_scores_gemma":[0.00002813151,0.0001929178,0.00003817818,0.0002013179,0.0001227854,0.00009843488,0.00006822894,0.0001528082,0.000003163974],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001041362,"about_ca_system_score_gemma":0.00004365314,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001141471,"about_ca_topic_score_gemma":0.001330208,"domain_scores_codex":[0.9987222,0.00003195979,0.0004396836,0.0003231443,0.0002306376,0.0002523874],"domain_scores_gemma":[0.9993483,0.00008786412,0.0002062779,0.0002511241,0.00005153843,0.00005487193],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000890435,0.00006248902,0.00344658,0.0002906582,0.00003995505,0.00001741891,0.0004638305,0.0000372629,0.9943796,0.00002841304,0.0001681984,0.0009765214],"study_design_scores_gemma":[0.001014143,0.00003796675,0.002728498,0.0000902899,0.00004440283,0.00002652422,0.0006785796,0.0000361476,0.9947831,0.00003142189,0.0003309715,0.0001979694],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982106,0.0003844019,0.0001317424,0.0007308181,0.00004906313,0.0001213294,0.00001133796,0.00003872914,0.0003219911],"genre_scores_gemma":[0.9988093,0.0001001971,0.0007200074,0.0001756975,0.00006278968,0.000007969588,0.00002085978,0.00004269273,0.00006044976],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009250998,"threshold_uncertainty_score":0.7866958,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008307531769354509,"score_gpt":0.2045832362895512,"score_spread":0.1962757045201967,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}