{"id":"W2068807017","doi":"10.1021/ol061772o","title":"[1,2]- or [2,3]-Rearrangement of Onium Ylides of Allyl and Benzyl Ethers and Sulfides via in Situ-Generated Iodonium Ylides","year":2006,"lang":"en","type":"article","venue":"Organic Letters","topic":"Cyclopropane Reaction Mechanisms","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Oxonium ion; Sulfonium; Chemistry; Ylide; Carbene; Carbenoid; Onium; Medicinal chemistry; Rhodium; Catalysis; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000102426,0.0004002711,0.0001325079,0.0001420387,0.0001117452,0.0001938056,0.0002338197,0.0001693429,0.002146531],"category_scores_gemma":[0.00009247253,0.0001124948,0.0001326482,0.0001069432,0.0001472868,0.000238938,0.0001736725,0.0001803771,0.000333778],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001916591,"about_ca_system_score_gemma":0.0002245018,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000396586,"about_ca_topic_score_gemma":0.0008003695,"domain_scores_codex":[0.9999551,0.000006423089,0.000003166728,0.000006430241,0.000006730338,0.00002215101],"domain_scores_gemma":[0.9999644,0.000004939083,0.0000122892,0.000006036798,0.000004025449,0.000008367767],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001204081,0.00002679292,0.0001807295,0.00007296925,0.000009231487,0.0003732578,0.00005773262,0.0004339066,0.9936453,0.001817528,0.0001497563,0.003112405],"study_design_scores_gemma":[0.00001879096,0.0001404116,0.0005828,0.000005653748,0.000008560115,0.0001704077,0.00003392062,0.0006823441,0.9954814,0.0001955609,0.002674171,0.000006125561],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9792615,0.0003993491,0.003126049,0.00006683441,0.00003958725,0.00003114356,0.0001005349,0.00006655195,0.01690848],"genre_scores_gemma":[0.9944893,0.0003495447,0.001288005,0.00002571647,0.000006290671,0.00001254739,0.0001172835,0.00001471452,0.003696639],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002146531,"threshold_uncertainty_score":0.00718087,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008307531769354509,"score_gpt":0.2045832362895512,"score_spread":0.1962757045201967,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}