{"id":"W2068993200","doi":"10.1073/pnas.1211209109","title":"Molecular response in one-photon absorption via natural thermal light vs. pulsed laser excitation","year":2012,"lang":"en","type":"article","venue":"Proceedings of the National Academy of Sciences","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":136,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Photon; Excitation; Absorption (acoustics); Laser; Physics; Radiation; Thermal; Optics; Atomic physics; Quantum mechanics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002751749,0.00009826803,0.000147505,0.0001599768,0.0001623712,0.0003212215,0.0003625515,0.0003336425,0.002460976],"category_scores_gemma":[0.0009343169,0.0000938945,0.0001449269,0.0001979551,0.0006498846,0.0004166919,0.0003110909,0.0004759017,0.0001988859],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002573814,"about_ca_system_score_gemma":0.0001783828,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002691305,"about_ca_topic_score_gemma":0.0001508449,"domain_scores_codex":[0.9998518,0.0000414057,0.000003920375,0.00002750667,0.00004459578,0.00003076538],"domain_scores_gemma":[0.9994727,0.0003647654,0.00005968618,0.00002880996,0.00004144771,0.00003255335],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003500781,0.00008252764,0.0007636971,0.0001209155,0.00001084644,0.000151459,0.0001546443,0.002662777,0.9877116,0.004678482,0.00009200567,0.003220955],"study_design_scores_gemma":[0.00008122198,0.001813661,0.01142907,0.00002755454,0.00003391799,0.0003737875,0.000392856,0.05573898,0.9254919,0.003611236,0.0009651449,0.00004076883],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950603,0.0001736485,0.002825526,0.00004911143,0.00001367924,0.00001058833,0.0000201202,0.00002754465,0.001819565],"genre_scores_gemma":[0.9983717,0.0001901899,0.0008883172,0.00002665529,0.000004789779,0.00001321378,0.00001736664,0.000007251627,0.0004806106],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002460976,"threshold_uncertainty_score":0.008232832,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02161783697959703,"score_gpt":0.2905770045124385,"score_spread":0.2689591675328414,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}