{"id":"W2069007834","doi":"10.1021/om049423q","title":"Unexpected Behavior of the Novel Organometallic Thioether C<sub>5</sub>H<sub>5</sub>FeC<sub>5</sub>H<sub>4</sub>C⋮CSC⋮CSiMe<sub>3</sub> toward Ru<sub>3</sub>(CO)<sub>12</sub>","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Crohn's and Colitis Foundation of Canada","keywords":"Chemistry; Thioether; Group 2 organometallic chemistry; Ruthenium; Crystallography; Stereochemistry; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaepi_narrow","sts","research_integrity","insufficient_payload"],"category_scores_codex":[0.004386685,0.009612635,0.01036085,0.004252219,0.003729066,0.002489873,0.01052064,0.005886438,0.002435216],"category_scores_gemma":[0.003059444,0.009541899,0.008231372,0.01459368,0.004823579,0.003637085,0.005450567,0.007729046,0.005839364],"about_ca_system_candidate":true,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.005142372,"about_ca_system_score_gemma":0.004167367,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002076897,"about_ca_topic_score_gemma":0.001694339,"domain_scores_codex":[0.9591795,0.001648529,0.01043257,0.01026187,0.008989249,0.009488282],"domain_scores_gemma":[0.9693269,0.002259919,0.007611758,0.01303269,0.003201137,0.004567642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0007743946,0.008597038,0.00140378,0.001699871,0.005847343,0.0004990135,0.002863853,0.0004803414,0.9253731,0.0006876229,0.001211963,0.05056171],"study_design_scores_gemma":[0.009142385,0.0007780435,0.01313022,0.001211971,0.008818461,0.0008342855,0.002031936,0.0002252219,0.9491532,0.00112532,0.003621496,0.0099275],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.974566,0.003892724,0.001579088,0.001805456,0.002861725,0.005245829,0.004192026,0.003044214,0.002812925],"genre_scores_gemma":[0.9768363,0.007943072,0.0005161063,0.001484719,0.003325689,0.001978782,0.003738962,0.003906077,0.0002702968],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04063421,"threshold_uncertainty_score":0.9986767,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02026882969939009,"score_gpt":0.2240562462307718,"score_spread":0.2037874165313817,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}