{"id":"W2069007834","doi":"10.1021/om049423q","title":"Unexpected Behavior of the Novel Organometallic Thioether C<sub>5</sub>H<sub>5</sub>FeC<sub>5</sub>H<sub>4</sub>C⋮CSC⋮CSiMe<sub>3</sub> toward Ru<sub>3</sub>(CO)<sub>12</sub>","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Crohn's and Colitis Foundation of Canada","keywords":"Chemistry; Thioether; Group 2 organometallic chemistry; Ruthenium; Crystallography; Stereochemistry; Molecule; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006966771,0.0002188167,0.00009023392,0.000120597,0.000146411,0.0002440273,0.000192767,0.0002467238,0.001511339],"category_scores_gemma":[0.0001931445,0.0001258093,0.00008823768,0.00007328684,0.000247501,0.000170783,0.00009679883,0.0002426799,0.0003638392],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001554452,"about_ca_system_score_gemma":0.0001055348,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004432313,"about_ca_topic_score_gemma":0.001084112,"domain_scores_codex":[0.9999288,0.000009334196,0.000003175788,0.00001578131,0.00002697109,0.00001589138],"domain_scores_gemma":[0.9999155,0.00002160553,0.00002232483,0.00001392586,0.00001397648,0.00001279082],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006681493,0.00000606493,0.0001683223,0.00003494103,0.000005749657,0.0001261809,0.00002895796,0.000102601,0.997215,0.0003219034,0.00009417116,0.001829294],"study_design_scores_gemma":[0.000002966493,0.00006318612,0.0006910918,0.000001050223,0.000005754136,0.0001730782,0.00001225514,0.0002945997,0.9976036,0.00004898451,0.001100832,0.000002707552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9864616,0.001231591,0.004893865,0.0001111104,0.00005392799,0.00001641799,0.0001201171,0.0002027571,0.006908495],"genre_scores_gemma":[0.9966428,0.0001429541,0.0009901705,0.00002123471,0.000003573351,0.000003325902,0.00005217994,0.000009825456,0.002133947],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001511339,"threshold_uncertainty_score":0.005055904,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02026882969939009,"score_gpt":0.2240562462307718,"score_spread":0.2037874165313817,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}