{"id":"W2069152275","doi":"10.1021/ol035125y","title":"Photolysis of Diacyl Peroxides:  A Radical-Based Approach for the Synthesis of Functionalized Amino Acids","year":2003,"lang":"en","type":"article","venue":"Organic Letters","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":42,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Photodissociation; Amino acid; Leucine; Component (thermodynamics); Photochemistry; Stereochemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000322905,0.0006984341,0.0002596024,0.000282764,0.0002020982,0.0002598503,0.0005902405,0.0004938433,0.0016587],"category_scores_gemma":[0.0001996132,0.0002938582,0.0002850224,0.0002418373,0.0003195696,0.0004689486,0.0003652716,0.00107889,0.0007059688],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002627399,"about_ca_system_score_gemma":0.0003021262,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001497765,"about_ca_topic_score_gemma":0.0002671642,"domain_scores_codex":[0.999889,0.00001711989,0.000009360166,0.00003083282,0.00002924771,0.00002435154],"domain_scores_gemma":[0.9999028,0.0000184033,0.00003375323,0.0000136339,0.0000129542,0.00001834601],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006158036,0.00002473766,0.00002632723,0.00009923095,0.000006013437,0.00009779254,0.0000225869,0.0001295324,0.9952325,0.0005615451,0.00009595165,0.003642185],"study_design_scores_gemma":[0.00002088003,0.0001439745,0.0001196724,0.000003826903,0.0000100697,0.0002378187,0.000004952276,0.0002211211,0.9967958,0.0001066778,0.002328356,0.00000682973],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8303186,0.008377274,0.1484347,0.0007129638,0.0004305058,0.0005395599,0.0005651094,0.0007465408,0.009874828],"genre_scores_gemma":[0.9303088,0.006730434,0.05399075,0.0002458148,0.00007043612,0.0001931685,0.0005141103,0.00009463305,0.007851882],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0016587,"threshold_uncertainty_score":0.005548954,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008083871721279504,"score_gpt":0.2035183169041752,"score_spread":0.1954344451828957,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}