{"id":"W2069294887","doi":"10.1351/pac-con-12-10-21","title":"Two-dimensional electronic spectroscopy for mapping molecular photophysics","year":2013,"lang":"en","type":"article","venue":"Pure and Applied Chemistry","topic":"Spectroscopy and Quantum Chemical Studies","field":"Physics and Astronomy","cited_by":26,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Air Force Office of Scientific Research; U.S. Air Force; Natural Sciences and Engineering Research Council of Canada; Defense Advanced Research Projects Agency","keywords":"Chemistry; Spectroscopy; Photosystem II; Ultrashort pulse; Chemical physics; Energy transfer; Conjugated system; Electron spectroscopy; Polymer; Electronic structure; Photochemistry; Computational chemistry; Photosynthesis; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00002888604,0.0002008097,0.0002132645,0.000006579102,0.0001426349,0.00004504542,0.00009184204,0.00004009366,0.0003742368],"category_scores_gemma":[0.000001352865,0.0001861789,0.00008152477,0.00006469906,0.0000608961,0.00003362676,0.00005655529,0.0001795833,0.00001542989],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002186435,"about_ca_system_score_gemma":0.00002669455,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001760027,"about_ca_topic_score_gemma":8.677193e-8,"domain_scores_codex":[0.9990051,0.00000188636,0.0001442397,0.0003136567,0.00009598168,0.0004390891],"domain_scores_gemma":[0.9996598,0.00003786847,0.00005927146,0.0001335293,0.0000279619,0.00008154677],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001026826,0.00004679844,0.0001169185,0.00003030051,0.00007710032,1.18463e-7,0.00002315086,0.000009451946,0.9805588,0.01757043,0.0008493698,0.0007072877],"study_design_scores_gemma":[0.0005200157,0.000008871164,0.00001625305,0.000007787269,0.00002253312,5.11652e-7,0.0001132138,0.0001961133,0.8870385,0.1109881,0.0008849351,0.0002030706],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9734169,0.0001823663,0.002580233,0.0001871894,0.00001700081,0.0002736041,0.00001682204,0.00003741477,0.02328842],"genre_scores_gemma":[0.9975743,0.000002359934,0.001314651,0.0001383607,0.0003636196,0.0003468269,0.00007138021,0.00002033423,0.0001681531],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.09352025,"threshold_uncertainty_score":0.7592157,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004327754785637438,"score_gpt":0.2161571878669491,"score_spread":0.2118294330813116,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}