{"id":"W2069370203","doi":"10.1021/om000809k","title":"Hexameric and Tetrameric Copper(I) Thioamidates","year":2001,"lang":"en","type":"article","venue":"Organometallics","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Random hexamer; Tetramer; Chemistry; Crystallography; Copper; Nuclear magnetic resonance spectroscopy; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001284578,0.0001566647,0.0003358014,0.00009699712,0.00008583562,0.00004395319,0.00007352294,0.00004834323,0.001324368],"category_scores_gemma":[0.0001261585,0.0001132138,0.00005961144,0.0003563067,0.000152962,0.00008492157,0.00005432681,0.0001216164,0.000232256],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001665723,"about_ca_system_score_gemma":0.0000276987,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002747803,"about_ca_topic_score_gemma":0.000002490042,"domain_scores_codex":[0.999139,0.0000328102,0.0001911352,0.0002355311,0.0001741555,0.0002273603],"domain_scores_gemma":[0.9994392,0.00006060093,0.00004744026,0.0002673687,0.00004326271,0.0001420677],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0002883024,0.0004588985,0.1428428,0.000282968,0.00038778,0.0001144457,0.0006870627,0.000001935965,0.6684157,0.002605728,0.00220877,0.1817056],"study_design_scores_gemma":[0.001069473,0.0008974279,0.2012346,0.00009555925,0.0003578436,0.001315706,0.0006368003,0.0004028269,0.02684658,0.0005366099,0.7659816,0.0006250113],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9655232,0.004028243,0.00008879192,0.001200523,0.00006956303,0.0001570436,0.000002437415,0.00008669592,0.02884348],"genre_scores_gemma":[0.988165,0.002467933,0.001977839,0.001118612,0.00009600385,0.000007140187,0.00001093441,0.00003224113,0.00612432],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7637728,"threshold_uncertainty_score":0.9995885,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03289697172555959,"score_gpt":0.2535227108150084,"score_spread":0.2206257390894488,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}