{"id":"W2069427052","doi":"10.1139/v05-122","title":"2003 Alcan Award Lecture Roles of the adjacent metals in the coupling of methylene groups promoted by heterobinuclear complexes of Group 8 and 9 metals","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":41,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Methylene; Chemistry; Osmium; Rhodium; Ruthenium; Medicinal chemistry; Alkyne; Ethylene; Diazomethane; Stereochemistry; Yield (engineering); Dimethyl acetylenedicarboxylate; Metal; Catalysis; Organic chemistry; Cycloaddition","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003781529,0.0003260588,0.0001805335,0.0002388214,0.0004374741,0.001085556,0.0005268425,0.0006901346,0.05127002],"category_scores_gemma":[0.0002283934,0.00009811961,0.0001552683,0.0001678631,0.0001808123,0.000386176,0.0004838624,0.0004926076,0.01173203],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001390062,"about_ca_system_score_gemma":0.0007651352,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001523398,"about_ca_topic_score_gemma":0.00593082,"domain_scores_codex":[0.99979,0.00002015605,0.000005372493,0.00003991537,0.00009161315,0.000052938],"domain_scores_gemma":[0.9997872,0.00001489696,0.0000093648,0.000008925795,0.00008064971,0.00009888442],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"not_applicable","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001453495,0.000411391,0.001779868,0.0002507044,0.00004249722,0.0008120594,0.0003636447,0.0013127,0.1171413,0.0284926,0.474483,0.3734567],"study_design_scores_gemma":[0.00003638293,0.000265096,0.001701085,0.00002442816,0.00001589374,0.0003012093,0.0002618947,0.001962343,0.0501776,0.002723384,0.9425108,0.00001989108],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.1671011,0.009073559,0.007082171,0.02975153,0.02267754,0.000154076,0.0005310906,0.0005452199,0.7630837],"genre_scores_gemma":[0.08304429,0.001839604,0.001260868,0.0004570081,0.0005928646,0.00001668314,0.00017458,0.0000591243,0.912555],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.05127002,"threshold_uncertainty_score":0.1715153,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008260210841363554,"score_gpt":0.2094789078979516,"score_spread":0.201218697056588,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}