{"id":"W2069462587","doi":"10.1021/jo901792t","title":"Supramolecular Complexation and Enantiodifferentiating Photocyclodimerization of 2-Anthracenecarboxylic Acid with 4-Aminoprolinol Derivatives as Chiral Hydrogen-Bonding Templates","year":2009,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":48,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Template; Supramolecular chemistry; Hydrogen bond; Chemistry; Hydrogen; Stereochemistry; Crystallography; Combinatorial chemistry; Materials science; Organic chemistry; Nanotechnology; Molecule","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001394069,0.000210764,0.0001981662,0.0000904486,0.0001049658,0.0001682575,0.0001842596,0.0001800922,0.0005515668],"category_scores_gemma":[0.000219988,0.0001018415,0.0001124159,0.0001361911,0.00016844,0.0001563836,0.000150442,0.0002774391,0.0001139443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000255985,"about_ca_system_score_gemma":0.0001327748,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003879988,"about_ca_topic_score_gemma":0.0007100698,"domain_scores_codex":[0.9998637,0.00002929133,0.00000947466,0.00003093197,0.00003274412,0.00003382787],"domain_scores_gemma":[0.9999191,0.00001813532,0.00002585668,0.0000133539,0.000006456038,0.00001709849],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005952756,0.00001879834,0.00006008422,0.00002296216,0.000003141832,0.00004318172,0.00002626866,0.0003902796,0.9974089,0.0002173701,0.00001956294,0.001729883],"study_design_scores_gemma":[0.000007777484,0.0000953156,0.0002063733,7.126075e-7,0.000002510587,0.00003106372,0.00000628225,0.0007090415,0.9984572,0.00001627474,0.000464365,0.000003117464],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969886,0.0003225302,0.001227781,0.0000250773,0.00001044667,0.0000201113,0.00003108522,0.00002148327,0.001352913],"genre_scores_gemma":[0.9980279,0.0001423029,0.001222339,0.00001119837,0.000002410559,0.000009082298,0.00003443583,0.000005275851,0.0005451983],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0005515668,"threshold_uncertainty_score":0.00185734,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03232806302434368,"score_gpt":0.3414157582111449,"score_spread":0.3090876951868012,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}