{"id":"W2069599932","doi":"10.1021/ja7105306","title":"A Lanthanide Phosphinidene Complex:  Synthesis, Structure, and Phospha-Wittig Reactivity","year":2008,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":157,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Phosphinidene; Chemistry; Reactivity (psychology); Lanthanide; Wittig reaction; Phosphine; Reagent; Phosphine oxide; Group (periodic table); Medicinal chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002034039,0.0003112277,0.0003284587,0.0002029937,0.0003382481,0.0005814058,0.0004708502,0.00045951,0.001498168],"category_scores_gemma":[0.0003208882,0.0002244983,0.0001316264,0.0002319477,0.0003141275,0.0005366903,0.0003239481,0.0005310678,0.0003587573],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006593553,"about_ca_system_score_gemma":0.0003192018,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006154126,"about_ca_topic_score_gemma":0.0007747074,"domain_scores_codex":[0.9998468,0.00001354821,0.00001361871,0.00004034217,0.00005344805,0.00003233035],"domain_scores_gemma":[0.9999081,0.00001372435,0.00001854908,0.00001636326,0.00001562501,0.00002758496],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001832219,0.0000501691,0.0001959218,0.0001248795,0.0000153689,0.0002178656,0.0001478839,0.0004068236,0.991935,0.002226516,0.0002215087,0.004274889],"study_design_scores_gemma":[0.00003397054,0.0001825889,0.0003423144,0.000003296061,0.000009233115,0.0002610591,0.00001622336,0.000423839,0.9943657,0.0001240897,0.004226517,0.00001118862],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.980971,0.001497466,0.009108305,0.0002448983,0.00004357505,0.0001325836,0.0002898363,0.0002362495,0.00747588],"genre_scores_gemma":[0.9891837,0.0006325931,0.004843927,0.0000434688,0.00000888218,0.00004027625,0.0003161179,0.00004375783,0.004887294],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001498168,"threshold_uncertainty_score":0.005011857,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01599568450959218,"score_gpt":0.2276853339609936,"score_spread":0.2116896494514014,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}