{"id":"W2069663629","doi":"10.1002/chem.200501237","title":"Wire‐Type Ruthenium(<scp>II</scp>) Complexes with Terpyridine‐Containing [2]Rotaxanes as Ligands: Synthesis, Characterization, and Photophysical Properties","year":2006,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Rotaxane; Chemistry; Photochemistry; Pyridinium; Ruthenium; Luminescence; Terpyridine; Photoinduced electron transfer; Crown ether; Chromophore; Crystallography; Electron transfer; Acetonitrile; Excited state; Supramolecular chemistry; Metal; Materials science; Crystal structure; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002273836,0.0005560534,0.0004664123,0.00003290742,0.0007982012,0.0005280793,0.0005275677,0.00009641071,0.0002175023],"category_scores_gemma":[0.000268588,0.0004618645,0.0001187786,0.0001692387,0.0003621446,0.0002532742,0.0002082765,0.0006590835,0.00002528246],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005394531,"about_ca_system_score_gemma":0.0001296629,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007463555,"about_ca_topic_score_gemma":3.423739e-7,"domain_scores_codex":[0.9977571,0.00006003452,0.0005805822,0.0005763327,0.0004427181,0.000583172],"domain_scores_gemma":[0.9984742,0.0001038166,0.0004514463,0.0004356283,0.0002269158,0.0003079883],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001429719,0.0001760774,0.001142931,0.0002238618,0.0001252242,0.0005267336,0.0003795209,0.00001245159,0.9963225,0.00001024778,0.0002999443,0.0006375281],"study_design_scores_gemma":[0.0007952355,0.00009561628,0.0003716055,0.0005979122,0.0001190206,0.003957015,0.0007817204,0.0002289137,0.9732674,0.00003542528,0.01941386,0.0003362856],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9859285,0.0004463968,0.0000700109,0.0001279931,0.00003737827,0.00006510736,0.00002088095,0.000183934,0.01311981],"genre_scores_gemma":[0.9928516,0.00006302215,0.0001544111,0.00008441616,0.001374722,0.00001527109,0.0001046466,0.0001253158,0.005226622],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02305512,"threshold_uncertainty_score":0.9997833,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01038352359573633,"score_gpt":0.1829516934993885,"score_spread":0.1725681699036522,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}