{"id":"W2070081770","doi":"10.1039/9781782620259-00228","title":"CHAPTER 5. Ancillary Ligand Design in the Development of Palladium Catalysts for Challenging Selective Monoarylation Reactions","year":2014,"lang":"en","type":"book-chapter","venue":"RSC catalysis series","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; Killam Trusts; Dalhousie University","keywords":"Palladium; Phosphine; Steric effects; Amination; Chemistry; Catalysis; Hydrazine (antidepressant); Ketone; Ligand (biochemistry); Combinatorial chemistry; Ammonia; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002123805,0.0007738172,0.0003941343,0.0006340176,0.0003691384,0.001448934,0.0006935007,0.0006681179,0.01932643],"category_scores_gemma":[0.0001519417,0.0004049431,0.0003233015,0.0009160636,0.0003338862,0.001245163,0.0007252548,0.002294459,0.01344739],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0007513242,"about_ca_system_score_gemma":0.0005278516,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004269451,"about_ca_topic_score_gemma":0.001027062,"domain_scores_codex":[0.9998618,0.0000117752,0.000006892481,0.00003472369,0.00007170099,0.00001293118],"domain_scores_gemma":[0.9999684,0.00001046691,0.000003501991,0.000003452353,0.000009233313,0.000005017394],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009649882,0.0002469967,0.00007315922,0.00371344,0.00002782927,0.0002428311,0.000441289,0.003474036,0.07822435,0.1340299,0.09359155,0.6858381],"study_design_scores_gemma":[0.000006332249,0.00005026748,0.00006188174,0.000255281,0.000007409371,0.0003179952,0.00002357253,0.0006198797,0.01790599,0.008354947,0.9723832,0.00001324569],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"other","genre_gemma":"methods","genre_scores_codex":[0.009594962,0.3718844,0.0866554,0.00217842,0.004663047,0.0003147348,0.0006422292,0.00157267,0.5224941],"genre_scores_gemma":[0.03515536,0.2786586,0.0560236,0.001783893,0.001202028,0.0003157952,0.0008236369,0.0005319088,0.6255052],"genre_candidate":"methods","genre_consensus":null,"teacher_disagreement_score":0.01932643,"threshold_uncertainty_score":0.06465334,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03210121234692339,"score_gpt":0.2531638310338577,"score_spread":0.2210626186869343,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}