{"id":"W2070145366","doi":"10.1021/ic700810f","title":"Dinitrogen Activation, Partial Reduction, and Formation of Coordinated Imide Promoted by a Chromium Diiminepyridine Complex","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":103,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba; University of Ottawa","funders":"","keywords":"Chemistry; Deprotonation; Ligand (biochemistry); Medicinal chemistry; Chromium; Imide; Stereochemistry; Polymer chemistry; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002017742,0.0002193588,0.000320064,0.00004476406,0.0001053255,0.00003016512,0.0002030594,0.0001371403,0.006603542],"category_scores_gemma":[0.0001890899,0.0002310142,0.00006894853,0.0004366931,0.0000895983,0.00013716,0.0001083691,0.0001268819,0.000008131631],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000131694,"about_ca_system_score_gemma":0.00003829524,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006634348,"about_ca_topic_score_gemma":0.000003168752,"domain_scores_codex":[0.9985598,0.000007403972,0.0005721958,0.0003384002,0.0002367459,0.0002854921],"domain_scores_gemma":[0.9989461,0.00005545896,0.0002738237,0.000374704,0.0001718118,0.0001781218],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006544057,0.0001348895,0.0002178521,0.0002026411,0.00007012172,7.920095e-7,0.0002419479,0.000001112519,0.9946253,0.000003015099,0.001017408,0.003419442],"study_design_scores_gemma":[0.0004748117,0.00001195287,0.0004346086,0.00003290658,0.00006982046,0.00004503215,0.000421033,0.0001175617,0.9899528,0.00001703304,0.008190797,0.0002316236],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9961315,0.00005605518,0.0006954108,0.0003704046,0.00001549155,0.0000904249,0.0000716818,0.00009334544,0.002475674],"genre_scores_gemma":[0.9985626,0.00001517546,0.0001497766,0.00001637635,0.0001668013,0.00001122048,0.00041504,0.00003247115,0.0006305429],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007173389,"threshold_uncertainty_score":0.9943045,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01199504135663927,"score_gpt":0.2208008170068997,"score_spread":0.2088057756502604,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}