{"id":"W2070149796","doi":"10.1139/v00-092","title":"Addition reactions of a dialkyl- and a diarylsilylene to cyanides RCN: Different pathways? (1)","year":2000,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Silylene; Ring (chemistry); Adamantane; Photodissociation; HEXA; Silicon; Stereochemistry; Crystallography; Ethylene; Medicinal chemistry; Photochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002255363,0.0003252246,0.0001974895,0.0001694616,0.0001657556,0.0001615734,0.000325095,0.0003020444,0.002386896],"category_scores_gemma":[0.0001984597,0.0001225859,0.0001762369,0.0001278778,0.0001923859,0.0004018795,0.0002353733,0.0002863879,0.0007358295],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005082253,"about_ca_system_score_gemma":0.0003594778,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001073889,"about_ca_topic_score_gemma":0.002542558,"domain_scores_codex":[0.9998324,0.000031375,0.00001028044,0.00003871274,0.00003109776,0.00005608839],"domain_scores_gemma":[0.9999193,0.00001502168,0.0000189868,0.00001247741,0.00001719764,0.00001709582],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003532087,0.00003931068,0.0002358715,0.000208493,0.00001656734,0.000289679,0.0001087535,0.0002325793,0.9913036,0.001042637,0.000271919,0.005897464],"study_design_scores_gemma":[0.000009678055,0.000117707,0.0003168505,0.000004882618,0.000005095446,0.0001304102,0.00001285421,0.0002909196,0.9959617,0.00004372331,0.003101778,0.000004339114],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9615235,0.002430521,0.008281589,0.0002165971,0.0001818022,0.0001570783,0.0004593545,0.0001709318,0.02657861],"genre_scores_gemma":[0.9854227,0.001215943,0.003618892,0.00006467176,0.00001650086,0.00003868432,0.000297123,0.00002829321,0.009297205],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002386896,"threshold_uncertainty_score":0.007984996,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01071150573140027,"score_gpt":0.1825665399408703,"score_spread":0.17185503420947,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}