{"id":"W2070223659","doi":"10.1039/b415019h","title":"Matrix-isolation pyrolysis investigation of mercapto-functionalized 1,3,4-thiadiazoles: thermal stability of thiadiazole lubricant additives","year":2005,"lang":"en","type":"article","venue":"Physical Chemistry Chemical Physics","topic":"Thermal and Kinetic Analysis","field":"Materials Science","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Thermal decomposition; Thermal stability; Acetonitrile; Pyrolysis; Matrix isolation; Chemistry; Organosulfur compounds; Sulfur; Thiadiazoles; Decomposition; Thermogravimetric analysis; Organic chemistry; Infrared spectroscopy; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001223201,0.0002811358,0.0001977374,0.000157365,0.0001856205,0.0001593396,0.0001731678,0.0001742085,0.0008409836],"category_scores_gemma":[0.0002236105,0.0001354557,0.000146974,0.0001837357,0.0001557876,0.0001791369,0.0001126026,0.0002135041,0.0001867843],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002119048,"about_ca_system_score_gemma":0.0002246675,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001364297,"about_ca_topic_score_gemma":0.002421755,"domain_scores_codex":[0.9999249,0.000009238021,0.000003539909,0.00001616918,0.00003196786,0.00001414808],"domain_scores_gemma":[0.9998569,0.00003224751,0.00003739414,0.00000913129,0.00005108951,0.00001309155],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003138241,0.000002145318,0.000103263,0.00001657022,0.000001520719,0.00001875236,0.00001227949,0.00003629327,0.9994134,0.00001221598,0.000003702531,0.0003485285],"study_design_scores_gemma":[0.000001154128,0.00004991928,0.001159589,0.000001223787,0.000003687941,0.00005796799,0.0000110028,0.0001793234,0.998292,0.000004062887,0.0002387904,0.000001184087],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968728,0.0009518691,0.001449734,0.00001487161,0.000004974889,0.000007521097,0.00008556729,0.00002212333,0.0005905275],"genre_scores_gemma":[0.996055,0.000691684,0.002159805,0.000007120285,0.000002254166,0.00000650147,0.0000947163,0.00001279405,0.0009701012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001364297,"threshold_uncertainty_score":0.002813399,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01270870180328951,"score_gpt":0.2329037299488047,"score_spread":0.2201950281455152,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}