{"id":"W2070545724","doi":"10.1002/anie.200900621","title":"Total Synthesis and Stereochemical Assignment of Micrococcin P1","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Canadian Institutes of Health Research; Natural Sciences and Engineering Research Council of Canada; University of British Columbia","keywords":"Total synthesis; Stereochemistry; Absolute configuration; Chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003468794,0.0005870733,0.0002714159,0.0006474497,0.0004444793,0.0003652493,0.0004284939,0.0002196332,0.001438782],"category_scores_gemma":[0.0004616798,0.0002209535,0.0001912093,0.0006290252,0.0005113571,0.0004118371,0.0005534563,0.0009072052,0.0007852146],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006052222,"about_ca_system_score_gemma":0.0009969524,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001266338,"about_ca_topic_score_gemma":0.00121087,"domain_scores_codex":[0.9998012,0.00003849397,0.0000106507,0.00003899098,0.00005636628,0.00005427789],"domain_scores_gemma":[0.9998419,0.00001971342,0.0000232256,0.0000356034,0.00004582405,0.00003375826],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005783128,0.0000650364,0.0002631993,0.0004083538,0.00002499756,0.0004728217,0.0002916323,0.002256264,0.8947669,0.01637655,0.001893263,0.08260271],"study_design_scores_gemma":[0.00002960044,0.0003687917,0.00041805,0.00001486569,0.00001855251,0.0002313238,0.00003521514,0.0006899129,0.9732882,0.001591146,0.02328715,0.00002703806],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7424188,0.01306103,0.183807,0.001284993,0.0007881779,0.0004329295,0.003720552,0.00106635,0.05342009],"genre_scores_gemma":[0.9274915,0.00905784,0.04984191,0.0001880686,0.0000911126,0.0001562877,0.001588543,0.0001737808,0.01141093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001438782,"threshold_uncertainty_score":0.004813254,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01108707039507135,"score_gpt":0.2496673345501102,"score_spread":0.2385802641550389,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}