{"id":"W2070545724","doi":"10.1002/anie.200900621","title":"Total Synthesis and Stereochemical Assignment of Micrococcin P1","year":2009,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Microbial Natural Products and Biosynthesis","field":"Medicine","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Canadian Institutes of Health Research; Natural Sciences and Engineering Research Council of Canada; University of British Columbia","keywords":"Total synthesis; Stereochemistry; Absolute configuration; Chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008636808,0.0001011946,0.0001688734,0.00006513602,0.00002036921,0.00001328483,0.00005253792,0.00006845547,0.0003816147],"category_scores_gemma":[0.0001622196,0.00008217698,0.00006484459,0.00005140127,0.00004629344,0.00009053812,0.00002162731,0.00009433351,0.000004685585],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006213841,"about_ca_system_score_gemma":0.00001737971,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001002694,"about_ca_topic_score_gemma":3.652922e-7,"domain_scores_codex":[0.9992907,0.000006469038,0.0002035504,0.0001981257,0.0002018995,0.00009926125],"domain_scores_gemma":[0.9995996,0.00005044178,0.0000851612,0.00009278885,0.0001129433,0.00005910257],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001649678,0.0001367542,0.0002140932,0.000026095,0.00004552319,0.000005577569,0.00003350067,1.106579e-7,0.9809035,0.00005698465,0.009810548,0.008602328],"study_design_scores_gemma":[0.0003542975,0.0000693074,0.006601245,0.0001585026,0.00005440197,0.00007805537,0.00002667899,0.000007284399,0.9900836,0.0001573803,0.002325681,0.00008357723],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9851369,0.0001756243,0.0001345711,0.0101397,0.0002652003,0.0001564768,0.0000754108,0.00002798419,0.003888125],"genre_scores_gemma":[0.9975875,0.000100237,0.0006292993,0.0004250609,0.0007721821,0.000001490745,0.00008849196,0.000005622679,0.0003901207],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01245059,"threshold_uncertainty_score":0.4178413,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01108707039507135,"score_gpt":0.2496673345501102,"score_spread":0.2385802641550389,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}