{"id":"W2071021570","doi":"10.1021/ja066522h","title":"Facile Photochemical Synthesis of Unprotected Aqueous Gold Nanoparticles","year":2006,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Gold and Silver Nanoparticles Synthesis and Applications","field":"Materials Science","cited_by":312,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Benzoin; Ketyl; Aqueous solution; Colloidal gold; Photochemistry; Nanoparticle; Radical; Chemical engineering; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002167277,0.0005687385,0.0002979286,0.0001840415,0.0002087437,0.0002536623,0.0004217811,0.0003312575,0.001367328],"category_scores_gemma":[0.0001745254,0.0003709186,0.0002093842,0.0001122302,0.0002360501,0.00024542,0.0002890663,0.0005287016,0.0007220171],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002582966,"about_ca_system_score_gemma":0.0002089709,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003301789,"about_ca_topic_score_gemma":0.0008996624,"domain_scores_codex":[0.9998444,0.00001185416,0.00001607791,0.00005096099,0.00004610734,0.00003052539],"domain_scores_gemma":[0.9998976,0.00002130235,0.00002292802,0.00002072562,0.00002311953,0.00001439825],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000009075723,0.000005555719,0.000007298901,0.00002435493,0.000001465912,0.00001805383,0.00001004093,0.00003563592,0.9987941,0.00008584806,0.00002652301,0.0009821876],"study_design_scores_gemma":[0.000003930988,0.0000364571,0.0000635094,9.329189e-7,0.000001987031,0.0000298056,0.000002527057,0.0001721789,0.9986841,0.00002421429,0.0009786334,0.000001648184],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8953104,0.003319664,0.08875838,0.0002573569,0.000289115,0.0002908928,0.0006279321,0.001056358,0.01008986],"genre_scores_gemma":[0.9464463,0.001643953,0.04121877,0.0001185787,0.00003757106,0.0001397605,0.0005207656,0.0001183554,0.009755834],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001367328,"threshold_uncertainty_score":0.00457418,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00783614549886318,"score_gpt":0.2176270220415667,"score_spread":0.2097908765427035,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}