{"id":"W2071297421","doi":"10.1021/om0601798","title":"First Detection of Methylgermylene in the Gas Phase and Time-Resolved Study of Some of Its Reactions","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthesis and characterization of novel inorganic/organometallic compounds","field":"Chemistry","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Flash photolysis; Reactivity (psychology); Reaction rate constant; Gas phase; Substituent; Kinetic energy; Photochemistry; Photodissociation; Analytical Chemistry (journal); Wavelength; Flash (photography); Phase (matter); Physical chemistry; Medicinal chemistry; Kinetics; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003188203,0.000177647,0.0004371205,0.0002033844,0.00006480609,0.00001745382,0.000262617,0.00009365612,0.00103194],"category_scores_gemma":[0.0001239127,0.0001495101,0.00007763217,0.0006352189,0.00008080259,0.0001567576,0.00006322179,0.0001211601,0.000003418848],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003142107,"about_ca_system_score_gemma":0.00002801481,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001363651,"about_ca_topic_score_gemma":0.0000707685,"domain_scores_codex":[0.9984645,0.0000549255,0.0007889086,0.0002369705,0.0003062174,0.0001484321],"domain_scores_gemma":[0.9986252,0.000281385,0.0005163403,0.000422608,0.0001247631,0.00002968615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000412806,0.0027126,0.0009435847,0.0001470568,0.00007692938,0.000001327662,0.0005316779,0.00001459588,0.9943212,0.0002436736,0.000002239902,0.00096381],"study_design_scores_gemma":[0.001799474,0.0002310149,0.01991714,0.00004693195,0.0001716153,0.000009910073,0.0009742156,0.0003448069,0.9742472,0.0001602388,0.001908287,0.0001891507],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985819,0.0002462899,0.00006058935,0.00007667964,0.00002874099,0.0001720185,0.00004623705,0.00001757027,0.0007700032],"genre_scores_gemma":[0.9994068,0.0001356623,0.00003906836,0.000006579528,0.00006134154,0.00001508712,0.00002153969,0.00002765135,0.0002862856],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02007401,"threshold_uncertainty_score":0.9998813,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01665188598341255,"score_gpt":0.2394837154049105,"score_spread":0.222831829421498,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}