{"id":"W2071405819","doi":"10.1021/jp804643c","title":"Influence of Molecular Dipole Moment on the Redox-Induced Reorganization of α-Helical Peptide Self-Assembled Monolayers: An Electrochemical SPR Investigation","year":2008,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"National Institute on Minority Health and Health Disparities; National Institute of General Medical Sciences","keywords":"Chronoamperometry; Monolayer; Self-assembled monolayer; Chemistry; Ferrocene; Peptide; Dipole; Cyclic voltammetry; Electrochemistry; Surface plasmon resonance; Electrolyte; Crystallography; Materials science; Nanotechnology; Organic chemistry; Electrode; Physical chemistry; Nanoparticle","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001208734,0.0001249593,0.0001913633,0.00002190844,0.00004801829,0.000005396583,0.0002520579,0.00006152724,0.00000531845],"category_scores_gemma":[0.00007313739,0.00007868696,0.00008312632,0.000247955,0.00004072229,0.00006828533,0.000019434,0.0003176822,9.891554e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00005819412,"about_ca_system_score_gemma":0.0000508402,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003658756,"about_ca_topic_score_gemma":7.424207e-8,"domain_scores_codex":[0.9991184,0.00005131068,0.0003051785,0.00007277315,0.0003350794,0.0001172639],"domain_scores_gemma":[0.9992497,0.0000686748,0.0001872646,0.0002525368,0.0001718441,0.00006999873],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003321788,0.00006243266,0.00002884454,0.00002869622,0.00006187646,0.000001963228,0.0003603132,0.02362935,0.9756433,0.00008227969,0.00005371625,0.00001402809],"study_design_scores_gemma":[0.0001876532,0.0001416821,0.0008534949,0.00003797261,0.00005805667,0.00004087294,0.00003487238,0.003377659,0.9947381,0.0004448815,0.00001011259,0.00007463001],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9993604,0.00003403839,0.0003309328,0.00009262316,0.000009482519,0.00006419064,7.487294e-7,0.00001768495,0.00008992545],"genre_scores_gemma":[0.9997141,0.00002108815,0.000122391,0.00002517413,0.00009394027,0.000001415743,0.00000164022,0.00001760512,0.000002684441],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02025169,"threshold_uncertainty_score":0.3208761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005153463158795125,"score_gpt":0.1938417684810893,"score_spread":0.1886883053222942,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}