{"id":"W2071415694","doi":"10.1016/j.jphotochem.2007.10.011","title":"Quenching of MgTPP and ZnTPP fluorescence by molecular oxygen","year":2007,"lang":"en","type":"article","venue":"Journal of Photochemistry and Photobiology A Chemistry","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":22,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Saskatchewan","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Quenching (fluorescence); Photochemistry; Chemistry; Acetonitrile; Solvent; Relaxation (psychology); Excited state; Diffusion; Oxygen; Reaction rate constant; Toluene; Chemical physics; Fluorescence; Analytical Chemistry (journal); Thermodynamics; Atomic physics; Kinetics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001825587,0.0002141912,0.0001510481,0.0001951366,0.0002532677,0.000293171,0.0005181523,0.000491477,0.002338398],"category_scores_gemma":[0.0003121551,0.0001254772,0.0001480501,0.0001683189,0.0003979746,0.0003779228,0.0002437217,0.000535721,0.0002571542],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005440047,"about_ca_system_score_gemma":0.0001414648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009883229,"about_ca_topic_score_gemma":0.0008312391,"domain_scores_codex":[0.9998882,0.00001276453,0.000003772066,0.00002210483,0.00002579028,0.00004741229],"domain_scores_gemma":[0.9998533,0.00006497691,0.00003043847,0.00001960243,0.0000121108,0.00001953886],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003588168,0.00002547278,0.0002200588,0.00004002351,0.000004093563,0.00009280008,0.00006120709,0.0001624324,0.9957859,0.0008658292,0.0001453181,0.002238041],"study_design_scores_gemma":[0.00001918711,0.00004314142,0.000966568,0.000002559128,0.000003201538,0.00005861181,0.00001397027,0.001041925,0.9970131,0.0000906633,0.0007443283,0.00000278676],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9951916,0.0003496285,0.002016356,0.000112615,0.00001123815,0.000007649191,0.00009504281,0.00007219968,0.002143712],"genre_scores_gemma":[0.9973809,0.0001376683,0.0006626318,0.000028073,0.000006487341,0.000009232022,0.0001537907,0.00001842985,0.001602647],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002338398,"threshold_uncertainty_score":0.007822752,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003502082446720049,"score_gpt":0.2245716794550153,"score_spread":0.2210695970082953,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}