{"id":"W2071553834","doi":"10.1021/ol016742u","title":"Photochemical Generation and Absolute Reactivity of an Allene Oxide in Solution","year":2001,"lang":"en","type":"article","venue":"Organic Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Allene; Chemistry; Photochemistry; Reaction rate constant; Nucleophile; Methanol; Reactivity (psychology); Oxide; Halide; Organic chemistry; Kinetics; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001077988,0.0001430623,0.0001730015,0.00003779776,0.00004124291,0.00001488143,0.0001051115,0.0001210547,0.0005397844],"category_scores_gemma":[0.00007867476,0.0001631671,0.00002872459,0.0001452459,0.00008029766,0.0001749116,0.00004835063,0.0002157872,0.000006708007],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000222299,"about_ca_system_score_gemma":0.00003414412,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001870884,"about_ca_topic_score_gemma":0.0001681177,"domain_scores_codex":[0.9990602,0.00001787422,0.0002397483,0.0003256758,0.0001522325,0.0002042598],"domain_scores_gemma":[0.9994392,0.00003678648,0.0001155771,0.0003079184,0.00002492406,0.00007554286],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002005242,0.0001210503,0.001843965,0.00002083031,0.00001425906,0.00001189716,0.0001040367,0.000002252027,0.9973201,0.000002748012,0.0001979043,0.0003408959],"study_design_scores_gemma":[0.0005646701,0.000006381186,0.003233808,0.00001751478,0.00001638265,0.00008749258,0.00005562316,0.0009281795,0.9947091,0.000009524852,0.0002154145,0.0001559061],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9981786,0.0000233413,0.0001954442,0.001062633,0.00002274581,0.00005343278,0.000007602211,0.00004646401,0.0004097169],"genre_scores_gemma":[0.9991005,0.00003188655,0.0004662916,0.0001212915,0.0001323892,0.000008889966,0.00005923055,0.00002583405,0.00005369854],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002611006,"threshold_uncertainty_score":0.6653761,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01681069021076808,"score_gpt":0.2355206464674458,"score_spread":0.2187099562566777,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}