{"id":"W2071553834","doi":"10.1021/ol016742u","title":"Photochemical Generation and Absolute Reactivity of an Allene Oxide in Solution","year":2001,"lang":"en","type":"article","venue":"Organic Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Allene; Chemistry; Photochemistry; Reaction rate constant; Nucleophile; Methanol; Reactivity (psychology); Oxide; Halide; Organic chemistry; Kinetics; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003948053,0.000369235,0.0001685738,0.0002312118,0.0002814259,0.0002505737,0.0003850506,0.0003978664,0.001044606],"category_scores_gemma":[0.0003636859,0.000251359,0.000164247,0.0001581653,0.0003005043,0.0004454468,0.0001999393,0.0008086389,0.0002649139],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002885767,"about_ca_system_score_gemma":0.0002225718,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008131345,"about_ca_topic_score_gemma":0.00140146,"domain_scores_codex":[0.9997734,0.00004063303,0.00001134251,0.00006200278,0.00007525504,0.00003737073],"domain_scores_gemma":[0.9998533,0.00005813422,0.00002834792,0.00001723047,0.00003120604,0.0000117687],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000216265,0.00000615595,0.00003854627,0.00005354867,0.000004692517,0.00002383264,0.00003906832,0.0001559838,0.9972109,0.0005824192,0.0000565987,0.001806641],"study_design_scores_gemma":[0.000005488619,0.0001288556,0.0001263019,0.000003937354,0.000005648542,0.00005476376,0.00001092573,0.000353784,0.9973724,0.00008679157,0.00184604,0.000004996863],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9445103,0.00764577,0.04082763,0.0001853354,0.00007416812,0.00008659413,0.000398966,0.0001289374,0.006142274],"genre_scores_gemma":[0.9745241,0.003563399,0.01744026,0.00004162066,0.00001886144,0.00007494971,0.0004367821,0.00002290489,0.003877113],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001044606,"threshold_uncertainty_score":0.003494561,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01681069021076808,"score_gpt":0.2355206464674458,"score_spread":0.2187099562566777,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}