{"id":"W2071697767","doi":"10.1002/chin.201252096","title":"ChemInform Abstract: Aziridine‐2‐carboxaldehyde Dimers Undergo Homo‐Ugi 4‐Component‐5‐center Reactions.","year":2012,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Aziridine; Chemistry; Enantiopure drug; Diastereomer; Component (thermodynamics); Ugi reaction; Bicyclic molecule; Stereochemistry; Combinatorial chemistry; Organic chemistry; Isocyanide; Ring (chemistry); Enantioselective synthesis; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001326866,0.0004326663,0.0001310955,0.0002389872,0.0002139469,0.0002581705,0.0003469644,0.0002073389,0.007383837],"category_scores_gemma":[0.00009950632,0.0001578588,0.000116615,0.0001788719,0.0001764784,0.0002412445,0.0003312733,0.0004171867,0.001949236],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003620202,"about_ca_system_score_gemma":0.0002020872,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004369252,"about_ca_topic_score_gemma":0.0008059534,"domain_scores_codex":[0.999915,0.0000106556,0.000003380301,0.0000205144,0.00002665009,0.00002372235],"domain_scores_gemma":[0.9999727,0.000002639694,0.000007488072,0.000006286796,0.000004671339,0.000006201026],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004334392,0.0000744243,0.0005291168,0.0001885606,0.00003563216,0.0003089907,0.0001641003,0.0006754171,0.9513425,0.006727207,0.002216745,0.03730394],"study_design_scores_gemma":[0.00003172032,0.0002531009,0.0008788303,0.000006479933,0.00001970322,0.0002974419,0.00001738162,0.000669063,0.9769338,0.0002264802,0.0206585,0.000007628634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8193863,0.004111756,0.0321384,0.0004347233,0.0002777029,0.0001706504,0.0008860821,0.001343628,0.1412508],"genre_scores_gemma":[0.9821077,0.0008395481,0.004063729,0.00004549192,0.00001514002,0.00002360666,0.000428065,0.00003614005,0.01244069],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007383837,"threshold_uncertainty_score":0.02470136,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02100149265460141,"score_gpt":0.2453058392239091,"score_spread":0.2243043465693077,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}