{"id":"W2071855396","doi":"10.1021/om900578d","title":"A Metal-Templated 4 + 2 Cycloaddition Reaction of an Alkyne and a Diyne To Form a 1,2-Aryne","year":2009,"lang":"en","type":"article","venue":"Organometallics","topic":"Cyclization and Aryne Chemistry","field":"Chemistry","cited_by":51,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"","keywords":"Aryne; Chemistry; Alkyne; Cycloaddition; Furan; Ring (chemistry); Metal; Template; Tungsten; Medicinal chemistry; Combinatorial chemistry; Stereochemistry; Organic chemistry; Nanotechnology; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001433789,0.0005761377,0.0003431264,0.0002725384,0.0001785929,0.0003345656,0.0004528597,0.0003649679,0.003535401],"category_scores_gemma":[0.0002074414,0.0003836815,0.0003392806,0.0001831214,0.0001316433,0.0003338693,0.0002917656,0.0004409239,0.001714126],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003819183,"about_ca_system_score_gemma":0.0003252004,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004436414,"about_ca_topic_score_gemma":0.001494264,"domain_scores_codex":[0.9998292,0.00001685349,0.00001253903,0.00005521864,0.00004797753,0.00003812741],"domain_scores_gemma":[0.9999233,0.00001453407,0.00001990885,0.00001706137,0.00001055579,0.00001457998],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007476678,0.0000374078,0.00009886256,0.00009994211,0.00001746696,0.0002440947,0.0000281124,0.0002981561,0.9922538,0.0007692121,0.000323343,0.005754744],"study_design_scores_gemma":[0.00002072261,0.0001645888,0.0004116404,0.000002788865,0.000007330359,0.0002950564,0.000005661768,0.0005332793,0.9931073,0.00008376704,0.00535816,0.000009852917],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8932056,0.002569509,0.04280843,0.0003306773,0.0005081606,0.0004952393,0.001333618,0.001294416,0.05745433],"genre_scores_gemma":[0.9569829,0.0007853947,0.02293708,0.00009242177,0.0000325367,0.0001284971,0.0005920303,0.00008360782,0.01836549],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003535401,"threshold_uncertainty_score":0.01182705,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009504590374629184,"score_gpt":0.2366473331821407,"score_spread":0.2271427428075115,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}