{"id":"W2071879060","doi":"10.1021/om700651g","title":"Chiral Hydride and Dihydrogen Pincer-Type Complexes of Osmium","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University","funders":"","keywords":"Chemistry; Pincer movement; Osmium; Hydride; Carbene; Yield (engineering); Dihydrogen complex; Pincer ligand; Ligand (biochemistry); Medicinal chemistry; Hydrogen; Stereochemistry; Crystallography; Ruthenium; Catalysis; Organic chemistry; Biochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000217832,0.0001455227,0.0002565572,0.00016543,0.00006518213,0.00001730968,0.0001912457,0.00009434327,0.00163711],"category_scores_gemma":[0.0001072427,0.0001398184,0.00007745146,0.0007455266,0.0001175497,0.00007661232,0.0001017048,0.0001032316,0.00004395302],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003752799,"about_ca_system_score_gemma":0.00002824283,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002942742,"about_ca_topic_score_gemma":0.00001939994,"domain_scores_codex":[0.9989393,0.000006587841,0.0003354836,0.0002248761,0.0002619364,0.0002318239],"domain_scores_gemma":[0.999285,0.00007294286,0.0001468729,0.0002845951,0.00007772755,0.0001328294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004668346,0.000228729,0.02444248,0.0001453323,0.0003357735,0.00001472818,0.0004852568,0.00001370453,0.9424186,0.003280886,0.0001461225,0.02844168],"study_design_scores_gemma":[0.0004138477,0.00002369458,0.002100109,0.000007417854,0.00009450049,0.00001671585,0.0001987494,0.0001938544,0.9664,0.0003665984,0.02995824,0.0002262428],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9606199,0.0006246701,0.0005362051,0.00005740732,0.00004045545,0.00003431396,0.00001874718,0.00005525687,0.03801309],"genre_scores_gemma":[0.9960917,0.0001018159,0.0004529993,0.00007460005,0.0000802986,9.351909e-7,0.00008175073,0.00002461689,0.003091287],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03547185,"threshold_uncertainty_score":0.9992755,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01062352001596499,"score_gpt":0.2394075422075263,"score_spread":0.2287840221915614,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}