{"id":"W2072022540","doi":"10.1016/j.tetlet.2004.06.071","title":"Stereoselective synthesis of the cis-decalin subunit of vinigrol via three pericyclic reactions in cascade","year":2004,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":30,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Pericyclic reaction; Decalin; Chemistry; Cascade; Cascade reaction; Tandem; Claisen rearrangement; Stereoselectivity; Ene reaction; Computational chemistry; Stereochemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001807894,0.0005219285,0.000286646,0.0002960293,0.0003017468,0.0004321597,0.0005295416,0.0002676081,0.002943316],"category_scores_gemma":[0.0001461023,0.0001744126,0.0002517901,0.0002507049,0.0002774661,0.0004868191,0.0005684854,0.000605269,0.001089547],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000461816,"about_ca_system_score_gemma":0.0004407825,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004414778,"about_ca_topic_score_gemma":0.000933268,"domain_scores_codex":[0.9998285,0.00001658833,0.00001028558,0.0000399024,0.00003086981,0.00007392442],"domain_scores_gemma":[0.9999313,0.000007159975,0.00001339846,0.00001629574,0.000008800615,0.00002300664],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003673346,0.0001259639,0.0004786435,0.0002181945,0.00002157826,0.001269788,0.0003326434,0.001191713,0.9423002,0.01499989,0.0008828138,0.03781135],"study_design_scores_gemma":[0.00004605304,0.0004955216,0.0008738277,0.00001106756,0.00002155671,0.0003885399,0.00005505302,0.0007345637,0.9790426,0.000977093,0.01733098,0.00002311394],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.91992,0.00172381,0.02227345,0.0003176364,0.0003092796,0.0001685225,0.0004824126,0.000427051,0.05437782],"genre_scores_gemma":[0.9838525,0.0007344498,0.006486797,0.00005690317,0.00002230588,0.00003372111,0.0002239253,0.00005490662,0.008534433],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002943316,"threshold_uncertainty_score":0.00984633,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01025278722100397,"score_gpt":0.2232240005816932,"score_spread":0.2129712133606892,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}