{"id":"W2072340926","doi":"10.1139/v10-030","title":"Theoretical study of the rovibrational spectrum of He<sub>2</sub>–OCS","year":2010,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Quantum, superfluid, helium dynamics","field":"Physics and Astronomy","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Rotational–vibrational spectroscopy; Lanczos resampling; Chemistry; Dipole; Microwave; van der Waals force; Atomic physics; Spectral line; Computational chemistry; Quantum mechanics; Physics; Eigenvalues and eigenvectors; Molecule","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001820906,0.0001138118,0.0002121806,0.00003390606,0.00006850899,0.00002141114,0.0004183476,0.00005885092,0.0009505668],"category_scores_gemma":[0.00004480592,0.0000899064,0.0001435092,0.0001216118,0.0003031883,0.00006374733,0.00002298394,0.0005309728,0.000001385998],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002959895,"about_ca_system_score_gemma":0.001496267,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004111316,"about_ca_topic_score_gemma":0.001267035,"domain_scores_codex":[0.9990347,0.00002483528,0.0004245268,0.00009284468,0.0002310207,0.0001920406],"domain_scores_gemma":[0.9989743,0.00005852012,0.0002516516,0.0002736899,0.0001655742,0.0002762565],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002169239,0.0002227306,0.2273625,0.00003342194,0.0002021851,0.00001297848,0.0007462807,0.0001667434,0.7366229,0.03363625,0.0005209427,0.000451376],"study_design_scores_gemma":[0.0009168704,0.00009935805,0.02761588,0.00005781845,0.00009599233,0.00004819698,0.001646188,0.0005813856,0.9470805,0.02152974,0.0001304663,0.000197634],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9967822,0.00001938441,0.00006608987,0.0004876126,0.0002377356,0.00006359084,0.00007437647,0.000001131925,0.002267825],"genre_scores_gemma":[0.9995277,3.66895e-7,0.00003204872,0.00001615242,0.0003880516,9.948404e-7,0.000003077901,0.00001407851,0.00001753617],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2104576,"threshold_uncertainty_score":0.9999627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00262584959746462,"score_gpt":0.1822284203103477,"score_spread":0.1796025707128831,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}