{"id":"W2072357435","doi":"10.1021/om800761c","title":"Probing the Dynamics and Reactivity of a Stereochemically Nonrigid Cp*Ru(H)(κ<sup>2</sup>-<i>P</i>,<i>C</i>arbene) Complex","year":2008,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; Dalhousie University","funders":"Natural Sciences and Engineering Research Council of Canada; McMaster University","keywords":"Chemistry; Hydride; Adduct; Reactivity (psychology); Indene; Borane; Medicinal chemistry; Reaction rate constant; Stereochemistry; Ruthenium; Nuclear magnetic resonance spectroscopy; Crystallography; Hydrogen; Kinetics; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000196068,0.000181078,0.0001878338,0.00009536862,0.0001480388,0.00040985,0.0004513853,0.0004125778,0.001064684],"category_scores_gemma":[0.0003611363,0.0002147093,0.00009985678,0.00009658639,0.0003101909,0.0002774534,0.0001936097,0.0003732665,0.0001873278],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004922954,"about_ca_system_score_gemma":0.0001283082,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007731048,"about_ca_topic_score_gemma":0.0008369276,"domain_scores_codex":[0.9998691,0.00001579637,0.000004081287,0.00003917141,0.00003361464,0.0000382535],"domain_scores_gemma":[0.9998646,0.00003487602,0.00004319336,0.00002194882,0.00001402898,0.00002135675],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002419862,0.00002711211,0.0007606737,0.00003342635,0.00001299939,0.00007954009,0.00009909664,0.0005819805,0.9964071,0.0004118205,0.00009247038,0.001251886],"study_design_scores_gemma":[0.00001242696,0.0001673303,0.002009035,0.000001427089,0.000006642835,0.00007665054,0.00002645344,0.002986529,0.9940218,0.00004392566,0.0006405003,0.000007216755],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9988356,0.00005465499,0.000542518,0.00001629526,0.000002368291,0.000004095697,0.00004410468,0.00001972203,0.0004805357],"genre_scores_gemma":[0.9993848,0.00002741606,0.0002241082,0.00000647633,8.636506e-7,0.000003501623,0.00004881031,0.000004556519,0.0002994603],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001064684,"threshold_uncertainty_score":0.003571808,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01851312672707714,"score_gpt":0.2200155989795431,"score_spread":0.201502472252466,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}