{"id":"W2072556497","doi":"10.1021/om050019g","title":"Diastereoselective Addition of Allyl- and Crotylstannanes to Dicobalt-Complexed Acetylenic Aldehydes","year":2005,"lang":"en","type":"article","venue":"Organometallics","topic":"Synthetic Organic Chemistry Methods","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Moiety; Nucleophile; Stereoselectivity; Allylic rearrangement; Triphenylphosphine; Reactivity (psychology); Medicinal chemistry; Nucleophilic addition; Metal carbonyl; Alcohol; Kinetic control; Aldehyde; Metal; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002296479,0.0005330444,0.0002262634,0.0002029508,0.0001252984,0.0002252698,0.0002650387,0.0002258729,0.001569598],"category_scores_gemma":[0.0002397762,0.0001563527,0.0001485392,0.0001593685,0.0002042322,0.0002675499,0.000310985,0.0003553871,0.0006569696],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003691496,"about_ca_system_score_gemma":0.0002483885,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004639496,"about_ca_topic_score_gemma":0.001416024,"domain_scores_codex":[0.9998212,0.00003209676,0.00001407393,0.00003531223,0.0000386262,0.00005864962],"domain_scores_gemma":[0.9998842,0.00001323908,0.00002139374,0.0000197487,0.00002350086,0.00003795161],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001373679,0.00002093798,0.00009835587,0.0000623714,0.000009545363,0.0001130355,0.00004718923,0.0002135087,0.9964025,0.0004374247,0.00006058108,0.002397332],"study_design_scores_gemma":[0.00001018234,0.00008581704,0.0001442387,0.000001476854,0.000004353982,0.00005129562,0.000008195512,0.0001864161,0.9984751,0.00002200792,0.00100774,0.000003012592],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9843889,0.0007828721,0.006687548,0.0000861349,0.00006804059,0.00008075574,0.0002313538,0.0001258974,0.007548575],"genre_scores_gemma":[0.9896856,0.0005586057,0.004808667,0.00003157778,0.000008630432,0.00002182601,0.0002129793,0.00003165162,0.004640348],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001569598,"threshold_uncertainty_score":0.005250812,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0116887333709489,"score_gpt":0.253403684343926,"score_spread":0.2417149509729771,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}