{"id":"W2072705611","doi":"10.1016/j.jpba.2005.07.040","title":"High performance liquid chromatographic determination of platinum in blood and urine samples of cancer patients after administration of cisplatin drug using solvent extraction and N,N′-bis(salicylidene)-1,2-propanediamine as complexation reagent","year":2005,"lang":"en","type":"article","venue":"Journal of Pharmaceutical and Biomedical Analysis","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":37,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University","funders":"","keywords":"Chemistry; Chromatography; High-performance liquid chromatography; Platinum; Urine; Elution; Reagent; Solvent; Cisplatin; Acetonitrile; Detection limit; Methanol; Quantitative analysis (chemistry); Biochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000272718,0.0003027412,0.0003285846,0.0006762561,0.0004273716,0.0002786798,0.0002571128,0.0005426712,0.0006584966],"category_scores_gemma":[0.001022907,0.0002209825,0.0002337889,0.0003783224,0.0002321512,0.000165691,0.0001308636,0.0005458848,0.0003018944],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001954164,"about_ca_system_score_gemma":0.0003450421,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00115279,"about_ca_topic_score_gemma":0.001814264,"domain_scores_codex":[0.9997036,0.00006771199,0.00002349653,0.00006462035,0.0001054533,0.00003507074],"domain_scores_gemma":[0.999696,0.0001036877,0.00004897503,0.00001937522,0.0000727868,0.00005910751],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.004604277,0.0007510644,0.1047363,0.000174366,0.0002326312,0.001545601,0.0003778953,0.0003000583,0.8433722,0.0002658032,0.0007846475,0.04285531],"study_design_scores_gemma":[0.0001813078,0.003615573,0.2610629,0.00002350842,0.0002435334,0.009078556,0.0001720435,0.0039183,0.7178494,0.0001979388,0.003617151,0.00003974827],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.986625,0.002348647,0.007850268,0.0002377447,0.0001255418,0.00009725511,0.0004652184,0.0002899965,0.001960452],"genre_scores_gemma":[0.9936725,0.0004212269,0.003573434,0.0002472598,0.00004635651,0.00005894229,0.0003623132,0.00001631334,0.001601607],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00115279,"threshold_uncertainty_score":0.002292216,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03876715846698774,"score_gpt":0.3392539596629571,"score_spread":0.3004868011959693,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}