{"id":"W2073247769","doi":"10.1002/chem.200601360","title":"Biaryls Made Easy: PEPPSI and the Kumada–Tamao–Corriu Reaction","year":2006,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":244,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphine; Chemistry; Yield (engineering); Protocol (science); Reactivity (psychology); Combinatorial chemistry; Catalysis; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0007965424,0.0002915501,0.0002490662,0.0000296694,0.000675608,0.0005195316,0.0003922231,0.00007676304,0.000725466],"category_scores_gemma":[0.0002594152,0.0002299802,0.0002118663,0.000131661,0.0004787342,0.000176432,0.0001327445,0.00114767,0.0001109635],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001640874,"about_ca_system_score_gemma":0.00008070771,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004469428,"about_ca_topic_score_gemma":0.000001605012,"domain_scores_codex":[0.9983045,0.00001002362,0.0005643443,0.0003648035,0.0003561839,0.0004001861],"domain_scores_gemma":[0.9985582,0.0001579913,0.0004159171,0.0005448171,0.0001243789,0.000198658],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001154795,0.00007141849,0.0004973651,0.00006107654,0.0000489399,0.000207627,0.0000982458,0.00003717965,0.9923807,0.00002863925,0.004735664,0.001717664],"study_design_scores_gemma":[0.01239583,0.00002397678,0.009626837,0.0005602591,0.0005636045,0.03699016,0.001568761,0.004367855,0.6764416,0.001070942,0.254967,0.001423135],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9395468,0.0004736863,0.00007115718,0.0006557011,0.0001811958,0.00004243564,0.00001988673,0.0001338035,0.05887533],"genre_scores_gemma":[0.9707429,0.000110917,0.00004430701,0.00005802369,0.002365169,0.000003741593,0.00004987614,0.00008093847,0.02654416],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3159391,"threshold_uncertainty_score":0.9378319,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007968894625064712,"score_gpt":0.2077366597078179,"score_spread":0.1997677650827532,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}