{"id":"W2073247769","doi":"10.1002/chem.200601360","title":"Biaryls Made Easy: PEPPSI and the Kumada–Tamao–Corriu Reaction","year":2006,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":244,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Phosphine; Chemistry; Yield (engineering); Protocol (science); Reactivity (psychology); Combinatorial chemistry; Catalysis; Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002762235,0.000508709,0.0003268951,0.0003289714,0.0002517454,0.0003325165,0.0004312151,0.0005819225,0.001280017],"category_scores_gemma":[0.0003388376,0.0003085701,0.0002053874,0.0003406789,0.0002839627,0.0005099448,0.0006552318,0.001084126,0.0008407848],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003077005,"about_ca_system_score_gemma":0.0002975417,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004769831,"about_ca_topic_score_gemma":0.0006689194,"domain_scores_codex":[0.9996374,0.00005105637,0.00003147046,0.00008247168,0.000136969,0.00006075209],"domain_scores_gemma":[0.999918,0.00001630543,0.00002038979,0.00001935335,0.00001089811,0.00001516135],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008380222,0.00004243635,0.0001270682,0.0002772764,0.0000172951,0.0003740811,0.0001015431,0.00045455,0.9804841,0.004517031,0.0003484805,0.01317239],"study_design_scores_gemma":[0.00001710834,0.0001494448,0.0002954964,0.000009810889,0.00001663594,0.0004339514,0.00001072673,0.0008267066,0.9889192,0.000280486,0.009027852,0.00001266108],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8037423,0.01589332,0.1323949,0.0007062764,0.000249476,0.0005739657,0.0006144961,0.00117758,0.04464769],"genre_scores_gemma":[0.945625,0.004717913,0.04073061,0.000142432,0.00004008536,0.0001644699,0.0004053458,0.00011808,0.00805609],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001280017,"threshold_uncertainty_score":0.004282057,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007968894625064712,"score_gpt":0.2077366597078179,"score_spread":0.1997677650827532,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}