{"id":"W2073256405","doi":"10.1039/c4cc09472g","title":"Photodriven [2]rotaxane–[2]catenane interconversion","year":2015,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Canadian Nautical Research Society","funders":"European Research Council","keywords":"Catenane; Rotaxane; Anthracene; Chemistry; Stereochemistry; Crystallography; Photochemistry; Molecule; Supramolecular chemistry; Organic chemistry; Crystal structure","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008197316,0.0001474665,0.0001538399,0.0000193155,0.00008910533,0.00003597528,0.001436598,0.0001301694,0.0004418202],"category_scores_gemma":[0.0002119756,0.0001499148,0.0000983709,0.0001295819,0.0002532972,0.00008346952,0.000762252,0.0003521148,0.0002291853],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001088899,"about_ca_system_score_gemma":0.00006351697,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003421006,"about_ca_topic_score_gemma":0.00000156938,"domain_scores_codex":[0.999155,0.0000223938,0.0002238516,0.0002161332,0.0001728845,0.0002096874],"domain_scores_gemma":[0.9976121,0.0001044365,0.00007537274,0.001860712,0.0001097034,0.0002376583],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002026758,0.0001505725,0.0002466016,0.00002230415,0.00002509896,0.000003127278,0.0002553823,6.962874e-7,0.9935873,0.0004479495,0.004085527,0.001155169],"study_design_scores_gemma":[0.0004188486,0.000004898726,0.000002143945,0.00003663113,0.00002195348,0.00003283385,0.0005484881,0.0004624905,0.872523,0.001215153,0.1245556,0.0001780211],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.731518,0.0009061734,0.0002135202,0.00185774,0.00004816765,0.00007638965,0.00002635786,0.0003540548,0.2649997],"genre_scores_gemma":[0.9954361,0.00003892503,0.002789859,0.000164955,0.00005592812,0.00005359321,0.0003448372,0.00002050964,0.001095238],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2639182,"threshold_uncertainty_score":0.6113349,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08251045622861002,"score_gpt":0.2859489791563762,"score_spread":0.2034385229277662,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}