{"id":"W2073387419","doi":"10.1021/ac501070a","title":"Sensing Parts-per-Trillion Cd<sup>2+</sup>, Hg<sup>2+</sup>, and Pb<sup>2+</sup> Collectively and Individually Using Phosphorothioate DNAzymes","year":2014,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":108,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Deoxyribozyme; Chemistry; Lanthanide; Metal; Selectivity; Detection limit; Cadmium; Cleavage (geology); Mercury (programming language); Substrate (aquarium); Catalysis; Inorganic chemistry; Combinatorial chemistry; Nanotechnology; Organic chemistry; Ion; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007598623,0.0008466062,0.0009596999,0.00013954,0.0005569248,0.0002830503,0.0003190995,0.0009243149,0.00002164937],"category_scores_gemma":[0.0007285241,0.0007930586,0.0003393731,0.0004918717,0.0008249375,0.00004056992,0.0004991121,0.0006139225,0.000005951286],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001166294,"about_ca_system_score_gemma":0.0001654394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007381633,"about_ca_topic_score_gemma":0.000005733836,"domain_scores_codex":[0.9957764,0.0001884982,0.0008196846,0.001641465,0.0005666896,0.001007336],"domain_scores_gemma":[0.9977795,0.0001639383,0.0002838927,0.0008496694,0.0003736191,0.0005494051],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001072143,0.0006457086,0.01689487,0.0007636979,0.002379585,0.0001666299,0.0009964614,0.009175411,0.934629,0.0001616685,0.007338263,0.02577651],"study_design_scores_gemma":[0.001550991,0.0003520031,0.0002621324,0.0002373506,0.0008242083,0.0004182508,0.000891116,0.2179803,0.7521617,0.0005263694,0.02314898,0.001646661],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9918448,0.0007444655,0.004649056,0.0004754465,0.0000173549,0.0002867472,0.00008406452,0.0001519156,0.001746169],"genre_scores_gemma":[0.9871274,0.0005127591,0.009301852,0.0006828425,0.0005853075,0.000006675346,0.0002325022,0.0001028669,0.001447842],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.2088048,"threshold_uncertainty_score":0.9994521,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01186249876219478,"score_gpt":0.2610576152514698,"score_spread":0.249195116489275,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}