{"id":"W2073387419","doi":"10.1021/ac501070a","title":"Sensing Parts-per-Trillion Cd<sup>2+</sup>, Hg<sup>2+</sup>, and Pb<sup>2+</sup> Collectively and Individually Using Phosphorothioate DNAzymes","year":2014,"lang":"en","type":"article","venue":"Analytical Chemistry","topic":"Advanced biosensing and bioanalysis techniques","field":"Biochemistry, Genetics and Molecular Biology","cited_by":108,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"","keywords":"Deoxyribozyme; Chemistry; Lanthanide; Metal; Selectivity; Detection limit; Cadmium; Cleavage (geology); Mercury (programming language); Substrate (aquarium); Catalysis; Inorganic chemistry; Combinatorial chemistry; Nanotechnology; Organic chemistry; Ion; Chromatography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000326536,0.0006982313,0.0004817332,0.0002760558,0.0001520622,0.0006345432,0.0008838632,0.0009181494,0.0007093513],"category_scores_gemma":[0.0005768057,0.0004260594,0.0002279718,0.0002811921,0.0003757403,0.0004910783,0.0004893314,0.0004623578,0.0005003824],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003632423,"about_ca_system_score_gemma":0.0002462615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000506077,"about_ca_topic_score_gemma":0.001160458,"domain_scores_codex":[0.9993753,0.00006510951,0.00003351173,0.0002769133,0.0002057637,0.00004346636],"domain_scores_gemma":[0.9997295,0.00007476466,0.00006542904,0.00002910588,0.00007419953,0.00002693549],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003765336,0.00001084412,0.0003137132,0.00003574805,0.000007582725,0.00001603254,0.00001546793,0.0001192499,0.9956956,0.00005880847,0.00005874945,0.003630619],"study_design_scores_gemma":[0.000004563286,0.00005154035,0.0004048969,0.000001970262,0.000009238807,0.00007372232,0.00001973762,0.001592421,0.9968033,0.00003655804,0.0009972076,0.000004793314],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8538144,0.003172842,0.1358623,0.0004731244,0.0001791158,0.0001604801,0.0006983695,0.001675881,0.003963523],"genre_scores_gemma":[0.8367755,0.001720253,0.1522505,0.0003661138,0.00006023974,0.000209242,0.0006007662,0.00008580971,0.007931554],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009181494,"threshold_uncertainty_score":0.002635539,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01186249876219478,"score_gpt":0.2610576152514698,"score_spread":0.249195116489275,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}