{"id":"W2073397663","doi":"10.1002/chin.200622013","title":"Syntheses of [F<sub>5</sub>TeNH<sub>3</sub>][AsF<sub>6</sub>], [F<sub>5</sub>TeN(H)Xe][AsF<sub>6</sub>], and F<sub>5</sub>TeNF<sub>2</sub> and Characterization by Multi‐NMR and Raman Spectroscopy and by Electronic Structure Calculations: The X‐Ray Crystal Structures of α‐ and β‐F<sub>5</sub>TeNH<sub>2</sub>, [F<sub>5</sub>TeNH<sub>3</sub>][AsF<sub>6</sub>], and [F<sub>5</sub>TeN(H)Xe][AsF<sub>6</sub>].","year":2006,"lang":"en","type":"article","venue":"ChemInform","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Chemistry; Raman spectroscopy; Characterization (materials science); Crystallography; X-ray; Crystal structure; Nanotechnology; Optics; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001916187,0.000360516,0.0002351538,0.0003623838,0.0003262594,0.0001501529,0.0004212623,0.0002473322,0.007559949],"category_scores_gemma":[0.0002333133,0.0001675102,0.0002123098,0.0003831,0.0001340771,0.0002750894,0.0001911796,0.0003244297,0.001239243],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004035546,"about_ca_system_score_gemma":0.0006343645,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.002422287,"about_ca_topic_score_gemma":0.009448372,"domain_scores_codex":[0.9999188,0.000006156381,0.000006965816,0.0000169812,0.0000354909,0.00001555649],"domain_scores_gemma":[0.9999377,0.000006230554,0.00001634684,0.000009685586,0.00001890019,0.0000111195],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002136491,0.0001111137,0.0002030576,0.001254323,0.00005115231,0.0001772903,0.0002587939,0.001332072,0.9626267,0.003144438,0.003033063,0.02759426],"study_design_scores_gemma":[0.00008844435,0.0006742388,0.001386279,0.00006290962,0.00004185536,0.0004315166,0.0001149016,0.001085829,0.9417198,0.0004775173,0.0538773,0.00003938804],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8043252,0.009544621,0.0610075,0.0005667845,0.0006638264,0.001347957,0.006299096,0.001129648,0.1151154],"genre_scores_gemma":[0.9119259,0.007139782,0.03802769,0.0002298849,0.00005057675,0.0004463464,0.003563583,0.0002054194,0.03841093],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007559949,"threshold_uncertainty_score":0.02529055,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003860260360551941,"score_gpt":0.1905312559630875,"score_spread":0.1866709956025356,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}