{"id":"W2073478914","doi":"10.1016/j.biortech.2007.08.008","title":"Reaction chemistry and phase behavior of lignin in high-temperature and supercritical water","year":2007,"lang":"en","type":"article","venue":"Bioresource Technology","topic":"Subcritical and Supercritical Water Processes","field":"Engineering","cited_by":387,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Saskatchewan","funders":"","keywords":"Phenol; Lignin; Chemistry; Supercritical fluid; Decomposition; Pyrolysis; Char; Chemical engineering; Phase (matter); Hydrolysis; Organic chemistry; Phenols; Polymerization; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001005821,0.0001222362,0.0001955397,0.0001082127,0.00002091511,0.000009122264,0.00006558895,0.0003843135,0.0000135828],"category_scores_gemma":[0.00005480993,0.00009765373,0.00001324811,0.0001384737,0.0003298573,0.00004951412,0.00004551077,0.0002687702,0.000002158763],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001498607,"about_ca_system_score_gemma":0.000002319872,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001298156,"about_ca_topic_score_gemma":0.000007733237,"domain_scores_codex":[0.9992317,0.000004638855,0.0002121261,0.0001791623,0.00006601052,0.0003063691],"domain_scores_gemma":[0.9997463,0.00004035512,8.306528e-7,0.0001073321,0.00002989519,0.0000753073],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001240159,0.00009138191,0.003929833,0.0001427308,0.000003478056,0.0000538914,0.000064342,7.700886e-8,0.9934625,0.0004810477,0.00001204717,0.001746283],"study_design_scores_gemma":[0.0005541106,0.00006065268,0.001852133,0.0000289655,0.00001494759,0.0001097032,0.000383997,0.00001447542,0.9960103,0.0005293031,0.0003140307,0.0001273565],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987705,0.0004645352,0.00001776717,0.0003738237,0.00002540849,0.00006876027,0.000007115317,0.0001583263,0.0001137161],"genre_scores_gemma":[0.9996409,0.00004262353,0.0002246656,0.00001942485,0.00002734424,0.00001358288,0.000007807647,0.00001623395,0.000007454459],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002547839,"threshold_uncertainty_score":0.3982204,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004451715638212882,"score_gpt":0.2212227942884744,"score_spread":0.2167710786502615,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}