{"id":"W2073753357","doi":"10.1002/anie.200461698","title":"Gas‐Phase Catalysis by Atomic and Cluster Metal Ions: The Ultimate Single‐Site Catalysts","year":2005,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":850,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Catalysis; Cluster (spacecraft); Chemistry; Ion; Gas phase; Chemical physics; Phase (matter); Oxidation state; Nanotechnology; Inorganic chemistry; Physical chemistry; Materials science; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001392846,0.000186097,0.0001523628,0.00007657754,0.0001666145,0.00009158695,0.0002750563,0.00009926935,0.002949632],"category_scores_gemma":[0.0000593517,0.0001482517,0.0000928566,0.0001382462,0.0001334638,0.0003091366,0.00009460554,0.0001814552,0.0000490259],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002054778,"about_ca_system_score_gemma":0.00001040625,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001211795,"about_ca_topic_score_gemma":0.00003780809,"domain_scores_codex":[0.9988624,0.000008380644,0.0003050331,0.0003385519,0.0003004201,0.0001851642],"domain_scores_gemma":[0.9992343,0.0001009835,0.0001830894,0.0002972606,0.0001099569,0.0000743631],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002657999,0.0002536631,0.00008289421,0.00001905933,0.000108056,0.000001157867,0.0001672489,0.00000151434,0.8949277,0.0008208096,0.1004477,0.003143643],"study_design_scores_gemma":[0.0005817354,0.0000123243,0.00001185982,0.00002632399,0.00007475095,0.00003901109,0.00005511184,0.000605753,0.8682244,0.001033364,0.1291822,0.0001531853],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8297796,0.001346377,0.005815501,0.04345781,0.0003361531,0.0004062955,0.002126358,0.0006182553,0.1161137],"genre_scores_gemma":[0.9918459,0.0002606767,0.0005270445,0.0004249001,0.001097627,0.0001732026,0.003645381,0.00002338642,0.002001893],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1620663,"threshold_uncertainty_score":0.9979618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01007231671290354,"score_gpt":0.2676995499352163,"score_spread":0.2576272332223128,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}