{"id":"W2073835830","doi":"10.1002/1521-3773(20020301)41:5<747::aid-anie747>3.0.co;2-j","title":"Introduction of Bulky Perfluoroalkyl Groups at the Periphery of Zinc Perfluorophthalocyanine: Chemical, Structural, Electronic, and Preliminary Photophysical and Biological Effects The financial assistance of Brown University start-up funds, Salomon Foundation, the US Department of Energy (ER 13235), and CIHR (MGP-377687) is gratefully acknowledged. The X-ray equipment at Brown University was purchased with assistance from NSF (CHE-8206423) and NIH (RR-06462). M. Beggs, I. Collosso, H. E. Ensley, T.-L. Shen, D. A. Sweigart, J. Van Epp, Jr., and C. La Madeleine are thanked for their contributions and assistance at various stages of this work. C. N. Tetzlaff is thanked for help with the graphical representation.","year":2002,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":58,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Sherbrooke","funders":"Division of Chemistry; Canadian Institutes of Health Research; U.S. Department of Energy; National Science Foundation; National Institutes of Health; Brown University","keywords":"Foundation (evidence); Zinc; Finance; Chemistry; Business; Political science; Law; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003019614,0.0002560665,0.0003787563,0.00003042506,0.0004714894,0.00003887931,0.0002213164,0.000127674,0.00007352835],"category_scores_gemma":[0.000108564,0.0001374758,0.0000692724,0.0001692758,0.00196052,0.0001655774,0.0002039843,0.0001451265,5.501784e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001508095,"about_ca_system_score_gemma":0.00004468944,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007579011,"about_ca_topic_score_gemma":0.0002074504,"domain_scores_codex":[0.998571,0.0001225347,0.0002888407,0.0004872592,0.0003217849,0.000208553],"domain_scores_gemma":[0.9976779,0.0009321631,0.0005730684,0.0002815893,0.0004765635,0.00005871194],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.007018659,0.0001783381,0.009291572,0.0001904382,0.000318281,0.000002872699,0.001930267,0.000009104237,0.9754441,0.0005043179,0.004710457,0.0004016184],"study_design_scores_gemma":[0.002510828,0.000541773,0.04988199,0.0001230025,0.0002571852,0.00003600483,0.0005628295,0.0002331187,0.9426565,0.0004460063,0.002569514,0.0001812223],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992294,0.002376244,0.000480576,0.002518297,0.00006018912,0.0006848396,0.0015537,0.000009136533,0.00002298051],"genre_scores_gemma":[0.9978464,0.0012718,0.0001046449,0.00004493276,0.0001255902,0.00004476012,0.0002801849,0.00001205367,0.0002696756],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04059042,"threshold_uncertainty_score":0.7223618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008191305977650743,"score_gpt":0.2058454486485528,"score_spread":0.197654142670902,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}