{"id":"W2073911984","doi":"10.1039/c2cs35213c","title":"Halogen bonding in solution: thermodynamics and applications","year":2012,"lang":"en","type":"review","venue":"Chemical Society Reviews","topic":"Crystallography and molecular interactions","field":"Chemistry","cited_by":565,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Halogen bond; Halogen; Chemistry; Covalent bond; Non-covalent interactions; Electrophile; Crystal engineering; Reactivity (psychology); Solid-state; Phase (matter); Computational chemistry; Crystal structure; Catalysis; Combinatorial chemistry; Molecule; Supramolecular chemistry; Physical chemistry; Organic chemistry; Hydrogen bond","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002121494,0.0003754857,0.001176076,0.00002439277,0.00008472922,0.00003247752,0.0002546034,0.0005601087,0.0001942318],"category_scores_gemma":[0.00002199588,0.0003196036,0.001345639,0.0003013586,0.0001210741,0.000058259,0.0001557534,0.0007741086,0.00002883536],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002084078,"about_ca_system_score_gemma":0.00003846761,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005827111,"about_ca_topic_score_gemma":0.00000245151,"domain_scores_codex":[0.9984251,0.00003268866,0.0006838409,0.000426367,0.00009443187,0.0003375836],"domain_scores_gemma":[0.999,0.00009816852,0.0003084968,0.0004460459,0.00001654008,0.0001308239],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[3.331595e-7,0.00007615584,0.00000330695,0.0210205,0.00008576151,4.44267e-7,0.00004923689,5.472949e-9,0.001895088,0.0007372648,0.0006419348,0.97549],"study_design_scores_gemma":[0.00005538779,7.706916e-7,6.894914e-8,0.003739092,0.0005660813,0.00004334879,0.00001301072,0.000004548324,0.00001749318,0.00007144605,0.9951873,0.0003014696],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.000002737304,0.9929684,0.0003120966,0.00001672935,0.00003052219,0.000490244,0.00005485028,0.00004174707,0.006082627],"genre_scores_gemma":[0.00001504016,0.9966637,0.0007230116,0.00004434246,0.0003152107,0.001270295,0.0005635471,0.0000440632,0.0003607725],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9945453,"threshold_uncertainty_score":0.9999256,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05385509806446222,"score_gpt":0.3274727741485713,"score_spread":0.2736176760841091,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}