{"id":"W2074005220","doi":"10.1139/v05-151","title":"Reactions of acetoxy(methylthio)carbene and <i>S</i>-methyl thiopyruvate","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reactions and Mechanisms","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Carbene; Chemistry; Thermal decomposition; Medicinal chemistry; Benzene; Transition metal carbene complex; Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001961377,0.0001541892,0.0002893036,0.00006355144,0.00008121146,0.00002797363,0.0002186389,0.000216522,0.001608946],"category_scores_gemma":[0.0003002155,0.000152335,0.0001425863,0.0001248075,0.000120764,0.0001345066,0.00001734424,0.0005180426,0.000003149851],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001835793,"about_ca_system_score_gemma":0.0007024677,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007423078,"about_ca_topic_score_gemma":0.0004825105,"domain_scores_codex":[0.9988821,0.000005708871,0.0005092007,0.0001485445,0.0001749244,0.0002795666],"domain_scores_gemma":[0.9982755,0.00008929802,0.0003708191,0.0002458889,0.0002207118,0.0007977489],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001077232,0.00001890466,0.0001669409,0.0001039635,0.00005295499,0.00001944936,0.0001441499,0.00001368752,0.9934904,0.00003490918,0.0007158415,0.005228057],"study_design_scores_gemma":[0.0003631066,0.000007814761,0.00002640579,0.000128786,0.00004328159,0.0003638949,0.0003238216,0.00001650875,0.8794017,0.0002913044,0.1189094,0.0001239799],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9623107,0.001159384,0.00004350313,0.0007244912,0.00007621552,0.00001643499,0.00004358276,0.000008896687,0.03561676],"genre_scores_gemma":[0.9946135,0.0002310434,0.001376081,0.000059615,0.0003578159,0.000001545942,0.000006187858,0.00002161645,0.003332614],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1181935,"threshold_uncertainty_score":0.9993037,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008409169241525119,"score_gpt":0.2150308911264938,"score_spread":0.2066217218849686,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}