{"id":"W2074082520","doi":"10.1016/j.chroma.2008.02.053","title":"Novel on-column and inverted operating modes of a microcounter-current flame ionization detector","year":2008,"lang":"en","type":"article","venue":"Journal of Chromatography A","topic":"Microfluidic and Capillary Electrophoresis Applications","field":"Engineering","cited_by":22,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Flame ionization detector; Chemistry; Analytical Chemistry (journal); Hydrogen; Gas chromatography; Detection limit; Capillary action; Chromatography; Thermal conductivity detector; Oxygen; Current (fluid); Premixed flame; Combustor; Combustion; Materials science; Thermodynamics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0009253954,0.001170866,0.0008599525,0.0009005681,0.000702721,0.001030375,0.004321595,0.001539245,0.004891237],"category_scores_gemma":[0.0008706391,0.001115082,0.000506339,0.000500861,0.000538384,0.001577913,0.001002937,0.001187929,0.002003546],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008837091,"about_ca_system_score_gemma":0.001394337,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001121226,"about_ca_topic_score_gemma":0.003664703,"domain_scores_codex":[0.9989114,0.00006545774,0.00005539243,0.0002856744,0.0005651063,0.0001169357],"domain_scores_gemma":[0.99924,0.0002120999,0.00007376271,0.00009802268,0.0002919,0.00008431239],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002185371,0.00007609285,0.0004396734,0.0001152798,0.00002978697,0.0000863439,0.00005855456,0.00007177656,0.9713056,0.00132884,0.001902542,0.02436707],"study_design_scores_gemma":[0.00004187944,0.0001656318,0.001468331,0.00001388989,0.00004733295,0.001012883,0.00001944309,0.005826044,0.9765926,0.000262173,0.01447931,0.00007037681],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"methods","genre_gemma":"empirical","genre_scores_codex":[0.2696961,0.00657254,0.6841499,0.002118932,0.001906887,0.0009542465,0.002085653,0.01272532,0.01979041],"genre_scores_gemma":[0.3724548,0.002188814,0.5946121,0.001877008,0.000748176,0.0006414058,0.001678498,0.0006211437,0.02517796],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.004891237,"threshold_uncertainty_score":0.01636285,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01003381352832952,"score_gpt":0.2027911937102621,"score_spread":0.1927573801819325,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}