{"id":"W2074199050","doi":"10.1021/ma021250y","title":"Helical Conjugated Polymers by Design","year":2002,"lang":"en","type":"article","venue":"Macromolecules","topic":"Synthesis and Properties of Aromatic Compounds","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université Laval","funders":"","keywords":"Conjugated system; Furan; Polymer; Circular dichroism; Side chain; Solvent; Chemistry; Phenylene; Materials science; Polymer chemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006181939,0.0001596435,0.0001788443,0.00002030313,0.0001058716,0.00007883138,0.0002596455,0.00008667885,0.01620296],"category_scores_gemma":[0.0000610799,0.0001451497,0.00007603123,0.00005815481,0.00009295942,0.00004035715,0.00005020166,0.00009523199,0.0004751006],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000024423,"about_ca_system_score_gemma":0.000006295797,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004213384,"about_ca_topic_score_gemma":5.595754e-7,"domain_scores_codex":[0.9990404,0.00003361659,0.0002092056,0.0002355841,0.0001947943,0.0002863856],"domain_scores_gemma":[0.9994122,0.0001163984,0.00004872949,0.0002941408,0.00001858825,0.000109927],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002641686,0.0001332551,0.00007654085,0.00003054971,0.00006599681,0.00003168176,0.000177431,0.000002598447,0.8903221,0.00005966805,0.05965184,0.04942188],"study_design_scores_gemma":[0.0004699706,0.00004620627,0.00001194267,0.00005485588,0.00002761258,0.00005026431,0.0001224031,0.003654571,0.9398243,0.0002317791,0.05513782,0.0003682152],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.6325578,0.007445868,0.001748775,0.002171317,0.0001040358,0.0001224229,0.00004987645,0.0005108296,0.355289],"genre_scores_gemma":[0.9931235,0.00007199573,0.000930552,0.0003522736,0.00004507981,0.00001865878,0.00001029284,0.00003213833,0.005415529],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3605656,"threshold_uncertainty_score":0.9846964,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0233607241209986,"score_gpt":0.2121034803435988,"score_spread":0.1887427562226002,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}