{"id":"W2074202913","doi":"10.1016/j.ica.2004.12.030","title":"Study of Pt(II)-cyclic amines complexes of the types cis- and trans-Pt(amine)2I2 and cis- and trans-Pt(amine)2(NO3)2 and their aqueous products by","year":2005,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":32,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Amine gas treating; Cyclohexylamine; Dimer; Aqueous solution; Cis–trans isomerism; Medicinal chemistry; Trimer; Aquation; Stereochemistry; Organic chemistry; Kinetics; Reaction rate constant","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00014241,0.000193913,0.0001499087,0.00008329286,0.0001839664,0.0001488173,0.0002352123,0.0001897073,0.00187835],"category_scores_gemma":[0.0002483177,0.0001468113,0.0001290209,0.0001004782,0.0002653261,0.0001775034,0.0001443271,0.0003438595,0.0002871233],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001371455,"about_ca_system_score_gemma":0.00009329749,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007931869,"about_ca_topic_score_gemma":0.0005943406,"domain_scores_codex":[0.999896,0.0000192568,0.000003636161,0.00002386422,0.0000352461,0.00002179183],"domain_scores_gemma":[0.999908,0.00003416112,0.00001750496,0.00001102558,0.00001811956,0.00001117269],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002420688,0.00001338964,0.0001449949,0.0000611705,0.00001225871,0.00007667255,0.00009210653,0.00009781491,0.9974434,0.0002343597,0.00006065131,0.001521111],"study_design_scores_gemma":[0.00001948659,0.0002250105,0.001049185,0.000002533634,0.00001634013,0.0001723492,0.0000289701,0.0007621741,0.9960226,0.00004406011,0.001653714,0.000003533335],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9924068,0.001251467,0.002321199,0.00006537961,0.00001860793,0.00001754116,0.00006182901,0.0000287088,0.003828567],"genre_scores_gemma":[0.9963284,0.0002590855,0.0006049994,0.00001552828,0.000009225006,0.000007601755,0.00007494196,0.000008487652,0.002691567],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00187835,"threshold_uncertainty_score":0.0062837,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02482761878822638,"score_gpt":0.2310519922522746,"score_spread":0.2062243734640482,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}