{"id":"W2074202913","doi":"10.1016/j.ica.2004.12.030","title":"Study of Pt(II)-cyclic amines complexes of the types cis- and trans-Pt(amine)2I2 and cis- and trans-Pt(amine)2(NO3)2 and their aqueous products by","year":2005,"lang":"en","type":"article","venue":"Inorganica Chimica Acta","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":32,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Amine gas treating; Cyclohexylamine; Dimer; Aqueous solution; Cis–trans isomerism; Medicinal chemistry; Trimer; Aquation; Stereochemistry; Organic chemistry; Kinetics; Reaction rate constant","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.000294579,0.0004492026,0.001048074,0.0001143706,0.00023912,0.0000451729,0.0002657507,0.0001354669,0.00005105326],"category_scores_gemma":[0.000213472,0.0002689077,0.00006869534,0.000260417,0.0006534682,0.0001504095,0.0001805896,0.000277182,4.617504e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001444242,"about_ca_system_score_gemma":0.00004253557,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001359521,"about_ca_topic_score_gemma":0.0003294842,"domain_scores_codex":[0.9978276,0.0002025627,0.0007064796,0.0006219367,0.0003125445,0.0003288322],"domain_scores_gemma":[0.9985499,0.0003041406,0.0002323424,0.0006309081,0.0001283739,0.000154295],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003822034,0.0006925036,0.005235385,0.0003820558,0.0002575722,9.006292e-7,0.008185488,9.424631e-8,0.9809272,0.00001743825,0.0004776495,0.00344151],"study_design_scores_gemma":[0.004382916,0.003436894,0.1304987,0.0003725519,0.000871207,0.0004090857,0.002788611,0.0001233448,0.8404456,0.0001234715,0.01587926,0.0006683552],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9872612,0.006271441,0.000003082054,0.004803089,0.00005384132,0.00109553,0.000102676,0.00004019294,0.000368917],"genre_scores_gemma":[0.9975295,0.001456336,0.0002030643,0.0002224897,0.0001210272,0.00001609046,0.00001100543,0.00006022192,0.0003802408],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1404816,"threshold_uncertainty_score":0.9999763,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02482761878822638,"score_gpt":0.2310519922522746,"score_spread":0.2062243734640482,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}