{"id":"W2074225716","doi":"10.1002/anie.200702816","title":"Heterolytic H<sub>2</sub> Activation by Nonmetals","year":2007,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":183,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"","keywords":"Heterolysis; Lewis acids and bases; Cleavage (geology); Chemistry; Transition metal; Frustrated Lewis pair; Nice; Photochemistry; Stereochemistry; Catalysis; Materials science; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008608927,0.0002141788,0.0001348482,0.0001111626,0.0001655533,0.0002969364,0.0004349154,0.0002858347,0.003087678],"category_scores_gemma":[0.00007835154,0.0001065433,0.0001370982,0.00008369413,0.0002547362,0.0004207136,0.0003262693,0.0002969973,0.0007461097],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000174562,"about_ca_system_score_gemma":0.00009108946,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001701503,"about_ca_topic_score_gemma":0.0003950041,"domain_scores_codex":[0.9999255,0.00001002675,0.000002698673,0.00001452489,0.00001999997,0.00002717227],"domain_scores_gemma":[0.9999679,0.000009096854,0.000005055095,0.000009372329,0.000002713203,0.000005838294],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00043132,0.00006574402,0.000305151,0.0001829252,0.00002459785,0.0004358485,0.0001160923,0.0006164266,0.9512681,0.01870633,0.002465295,0.02538223],"study_design_scores_gemma":[0.00003416112,0.000181684,0.0005372426,0.00000355778,0.000006532816,0.0004563043,0.00003168231,0.000847027,0.9832745,0.00195265,0.0126617,0.00001294382],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.922797,0.002402175,0.01386836,0.0004130155,0.0001866477,0.00003738937,0.0002705782,0.0005049342,0.05951985],"genre_scores_gemma":[0.9904084,0.0004234207,0.002333995,0.00008693005,0.00001711017,0.00001285413,0.00008793463,0.00003035391,0.006598891],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003087678,"threshold_uncertainty_score":0.01032931,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008662262593943147,"score_gpt":0.2371351008645736,"score_spread":0.2284728382706304,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}