{"id":"W2074261326","doi":"10.1139/v02-085","title":"The synthesis of [{<i>n</i>-Bu<sub>2</sub>Sn(S<sub>2</sub>N<sub>2</sub>)}<sub>2</sub>] and its use in the preparation of organometallic iridium sulfur nitrogen complexes","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Iridium; Yield (engineering); Bimetallic strip; Tin; Reagent; Sulfur; Medicinal chemistry; Ammonia; Metathesis; Molar ratio; Nitrogen; Salt metathesis reaction; Inorganic chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.001495726,0.001076517,0.001785404,0.0004657312,0.0006693008,0.000485271,0.001948936,0.0006188264,0.0005621374],"category_scores_gemma":[0.001897008,0.0009134295,0.0009682621,0.001379042,0.0008909029,0.0007255243,0.0001943771,0.001180333,0.00003849644],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006172456,"about_ca_system_score_gemma":0.001110813,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002227633,"about_ca_topic_score_gemma":0.003578813,"domain_scores_codex":[0.993246,0.0003195666,0.002697902,0.0009674124,0.001350448,0.001418734],"domain_scores_gemma":[0.9924514,0.001559663,0.002298207,0.001636427,0.000872108,0.001182166],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001279184,0.0002596766,0.001398629,0.0005416925,0.0008006945,0.0001428154,0.0008059858,0.00008352375,0.986762,0.00003050712,0.001265817,0.007780706],"study_design_scores_gemma":[0.0009070588,0.00006992622,0.00145257,0.0004527862,0.0007839157,0.0006272821,0.001146257,0.00023539,0.9914231,0.0002465617,0.001776984,0.0008781315],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9922687,0.004878984,0.00001152197,0.0008197026,0.0001322944,0.0003413606,0.0005972746,0.00003664837,0.0009135232],"genre_scores_gemma":[0.9966513,0.002281831,0.00002532006,0.0001392023,0.0005399027,0.00006247649,0.00007739176,0.0001764787,0.00004607846],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006902575,"threshold_uncertainty_score":0.9993317,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01642788110057196,"score_gpt":0.2019468944000474,"score_spread":0.1855190132994754,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}